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Merck

14694

Sigma-Aldrich

双(1,5-环辛二烯)四氟硼酸铑(I)

别名:

四氟硼酸铑(I) 1,5-环辛二烯络合物

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100 MG
$188.00

$188.00


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100 MG
$188.00

About This Item

经验公式(希尔记法):
C16H24BF4Rh
CAS号:
分子量:
406.07
MDL號碼:
分類程式碼代碼:
12161600
PubChem物質ID:
NACRES:
NA.22

$188.00


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成份

carbon content, 45.7-49.0%

反應適用性

core: rhodium
reagent type: catalyst

mp

~190 °C (dec.)

SMILES 字串

[Rh+].F[B-](F)(F)F.C1CC=CCCC=C1.C2CC=CCCC=C2

InChI

1S/2C8H12.BF4.Rh/c2*1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h2*1-2,7-8H,3-6H2;;/q;;-1;+1/b2*2-1-,8-7-;;

InChI 密鑰

NBGSCPNNKGVTKU-QMDOQEJBSA-N

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包裝

无底玻璃瓶。内含物装在插入的融合锥内。

其他說明

用于使用膦配体制备阳离子 COD-Rh 络合物(例如不对称加氢)的铑配合物[1][2][3];氢化硅烷化反应[4]

象形圖

Health hazardExclamation mark

訊號詞

Danger

危險分類

Acute Tox. 4 Oral - Eye Irrit. 2 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

4.1B - Flammable solid hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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U. Nagel et al.
Chemische Berichte, 119, 3326-3326 (1986)
R. Takeuchi et al.
The Journal of Organic Chemistry, 60, 3045-3045 (1995)
I. Ojima et al.
Tetrahedron, 45, 6901-6901 (1989)
M. Sawamura et al.
Journal of the American Chemical Society, 117, 9602-9602 (1995)

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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