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Merck
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文件

137561

Sigma-Aldrich

3-甲基-1-戊炔-3-醇

98%

别名:

催眠醇, 甲基乙基乙炔基甲醇

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About This Item

线性分子式:
CH≡CC(OH)(CH3)CH2CH3
CAS号:
77-75-8
分子量:
98.14
Beilstein:
969340
EC號碼:
201-055-5
MDL號碼:
MFCD00004479
分類程式碼代碼:
12352100
PubChem物質ID:
24848336
NACRES:
NA.22

蒸汽密度

3 (vs air)

蒸汽壓力

6.5 mmHg ( 20 °C)

化驗

98%

形狀

liquid

折射率

n20/D 1.431 (lit.)

bp

121-122 °C (lit.)

溶解度

Cellosolve: miscible
Stoddard solvent: miscible
acetone: miscible
benzene: miscible
carbon tetrachloride: miscible
cyclohexanone: miscible
diethyl ether: soluble
diethylene glycol: miscible
ethanolamine: miscible
ethyl acetate: miscible
kerosene: miscible
mineral spirits: miscible
neatsfoot oil: miscible
petroleum ether: miscible
soybean oil: miscible

密度

0.866 g/mL at 25 °C (lit.)

SMILES 字串

CCC(C)(O)C#C

InChI

1S/C6H10O/c1-4-6(3,7)5-2/h1,7H,5H2,2-3H3

InChI 密鑰

QXLPXWSKPNOQLE-UHFFFAOYSA-N

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一般說明

3-Methyl-1-pentyn-3-ol acts as initiator during the synthesis of propargyl-terminated polylactide by bulk ring-opening polymerization.

應用

3-Methyl-1-pentyn-3-ol is propargyl alcohol that can be used as:
  • A reactant to synthesize α-methylene cyclic carbonates by reacting with carbon dioxide.
  • A reactant in the synthesis of 2,6,9-trisubstituted purine based CDK inhibitors.
  • An initiator in the synthesis of polylactide bearing terminal propargyl group via ring-opening polymerization of L-lactide.

生化／生理作用

3-Methyl-1-pentyn-3-ol is a sedative and induces hepatic P4503A in mouse.

訊號詞

Danger

危險分類

Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Flam. Liq. 3

儲存類別代碼

3 - Flammable liquids

水污染物質分類（WGK）

WGK 2

閃點（°F）

82.4 °F - closed cup

閃點（°C）

28 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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炔丙醇 99%

Sigma-Aldrich

P50803

炔丙醇

3-丁炔-1-醇 97%

Sigma-Aldrich

130850

3-丁炔-1-醇

异丙醇铝 ≥98%

Sigma-Aldrich

220418

异丙醇铝

H Teräväinen et al.
Journal of neurology, neurosurgery, and psychiatry, 49(2), 198-199 (1986-02-01)
Six patients with essential tremor tested in the therapeutic effectiveness of a 6-carbon alcohol, methylpentynol, 200 mg/day, against placebo in a randomised double-blind clinical cross-over trial. The effect of methylpentynol on postural tremor amplitude was not different from that of
Preparation of propargyl-terminated polylactide by the bulk ring-opening polymerization.
Liu X, et al.
Journal of Macromolecular Science, Part A: Pure and Applied Chemistry, 46(10), 937-942 (2009)
M I Walash et al.
Journal - Association of Official Analytical Chemists, 68(6), 1209-1212 (1985-11-01)
Titrimetric and spectrophotometric titration methods are described for the quantitative determination of acetylenic hypnotics ethchlorvynol, ethinamate, and meparfynol carbamate as pure substances and in dosage forms. The methods involve the use of different brominating agents. A known excess of the
Cyclin-dependent kinase (CDK) inhibitors: development of a general strategy for the construction of 2, 6, 9-trisubstituted purine libraries. Part 3
Brun V, et al.
Tetrahedron Letters, 42(46), 8169-8171 (2001)
A el-Brashy et al.
Pharmaceutisch weekblad. Scientific edition, 10(2), 90-92 (1988-04-22)
A titrimetric method is described for the determination of three acetylenic hypnotics, namely ethchlorvynol, ethinamate, and methylpentynol carbamate, in bulk and in dosage forms. The method involves the use of either 1,3-dibromo-5,5-dimethylhydantoin (DBH), N-bromosuccinimide (NBS) or N-bromophthalimide (NBP) as titrants.
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