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Merck

130850

Sigma-Aldrich

3-丁炔-1-醇

97%

别名:

3-Butynol

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$87.10
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$295.00
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国内现货,预计发货时间2025年4月23日详情


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5 G
$87.10
25 G
$295.00
100 G
$990.00

About This Item

线性分子式:
HC≡CCH2CH2OH
CAS号:
分子量:
70.09
Beilstein:
773710
EC 号:
MDL编号:
UNSPSC代码:
12352100
eCl@ss:
39020335
PubChem化学物质编号:
NACRES:
NA.22

$87.10


国内现货,预计发货时间2025年4月23日详情


获取大包装报价

质量水平

方案

97%

表单

liquid

折射率

n20/D 1.441 (lit.)

沸点

128.9 °C (lit.)

mp

−63.6 °C (lit.)

密度

0.926 g/mL at 25 °C (lit.)

官能团

hydroxyl

SMILES字符串

OCCC#C

InChI

1S/C4H6O/c1-2-3-4-5/h1,5H,3-4H2

InChI key

OTJZCIYGRUNXTP-UHFFFAOYSA-N

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一般描述

3-丁炔-1-醇的燃烧和汽化焓用静态燃烧量热法和相关气相色谱法测量 [1]

应用

3-丁炔-1-醇用于制备马氏加成物 [2]
合成元用于制备含氧杂环[3] 和受保护的s-羟基-L-异亮氨酸酯
在钯催化偶合 β-tetrionic酸溴化物的研究中,使用炔基底物,可使生成炔基取代呋喃酮的产量很高。 [4]

象形图

FlameExclamation mark

警示用语:

Warning

危险分类

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

3 - Flammable liquids

WGK

WGK 3

闪点(°F)

96.8 °F - closed cup

闪点(°C)

36 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Tetrahedron Letters, 48, 105-105 (2007)
Kopf, Henning; Pietraszuk. et al.
Organometallics, 25(10), 2533-2546 (2006)
Ederley Vélez et al.
The journal of physical chemistry. A, 109(34), 7832-7838 (2006-07-13)
The enthalpies of combustion and vaporization of 3-buten-1-ol and 3-butyn-1-ol have been measured by static bomb combustion calorimetry and correlation gas chromatography techniques, respectively, and the gas-phase enthalpies of formation, Delta(f)H degrees (m)(g), have been determined, the values being -147.3
Sumod A Pullarkat et al.
Inorganic chemistry, 45(18), 7455-7463 (2006-08-29)
Alcohol functionalized diphosphine ligands with chirality residing on the carbon backbone were prepared using a novel two-stage asymmetric synthetic methodology from the corresponding terminal alkynols. Under mild conditions, the alkynols, 3-butyn-1-ol and 2-propyn-1-ol, were subjected to direct hydrophosphination to give
Deniz Dogruer et al.
Bioorganic & medicinal chemistry letters, 14(2), 523-526 (2003-12-31)
The binding of a series pyridylbutynylamines 6 was examined at alpha4beta2 nACh receptors. Structural modifications, comparing 6 with pyridyl ethers 2, did not consistently result in parallel effects on receptor affinity, suggesting possible differences in their modes of binding. Furthermore

商品

Alkynes' versatility enables reactions like addition, metathesis, hydroboration, cleavage, coupling, and cycloadditions in synthetic chemistry.

相关内容

Alkynes contain a highly versatile functional group that may be utilized for numerous reactions such as electrophilic additions of hydrogen, halogens, hydrogen halides, or water; metathesis; hydroboration; oxidative cleavage; C–C coupling; and cycloadditions

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

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    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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