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40263

N,N-Dimethylformamide di-tert-butyl acetal

technical, ≥90% (GC)

Synonym(s):

1,1-Di-tert-butoxy-N,N-dimethylmethylamine, 1,1-Di-tert-butoxytrimethylamine

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10 mL

Available to ship TODAYfromMILWAUKEE

$446.00
$334.50
50 mL

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$962.00
$721.50

About This Item

Linear Formula:
(CH3)2NCH[OC(CH3)3]2
CAS Number:
36805-97-7
Molecular Weight:
203.32
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
329755963
EC Number:
253-222-7
Beilstein/REAXYS Number:
969629
MDL number:
MFCD00015002
Assay:
≥90% (GC)
Form:
liquid

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grade

technical

Quality Segment

100

assay

≥90% (GC)

form

liquid

bp

56-57 °C/8 mmHg (lit.)

density

0.848 g/mL at 25 °C (lit.)

functional group

amine, ether

SMILES string

CN(C)C(OC(C)(C)C)OC(C)(C)C

InChI

1S/C11H25NO2/c1-10(2,3)13-9(12(7)8)14-11(4,5)6/h9H,1-8H3

InChI key

DBNQIOANXZVWIP-UHFFFAOYSA-N

Application

N,N-Dimethylformamide di-tert-butyl acetal may be used in the synthesis of following:
  • (S)-2-(1-tert-butoxycarbonyl-2-{4-[2-(5-methyl-2-phenyloxazol-4-yl)ethoxy]phenyl}ethylamino)benzoic acid methyl ester[1]
  • 3-O-tert-butylmorphine[2]
  • tert-butylesters of pyrrole- and indolecarboxylic acids

Other Notes

Review; synthesis of tert-butyl esters.

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This Item
140244178535142778
N,N-Dimethylformamide di-tert-butyl acetal technical, ≥90% (GC)

Sigma-Aldrich

40263

N,N-Dimethylformamide di-tert-butyl acetal

N,N-Dimethylformamide dineopentyl acetal 99%

Sigma-Aldrich

140244

N,N-Dimethylformamide dineopentyl acetal

N,N-Dimethylformamide diisopropyl acetal 95%

Sigma-Aldrich

178535

N,N-Dimethylformamide diisopropyl acetal

N,N-Dimethylformamide diethyl acetal 95%

Sigma-Aldrich

142778

N,N-Dimethylformamide diethyl acetal

assay

≥90% (GC)

assay

99%

assay

95%

assay

95%

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

density

0.848 g/mL at 25 °C (lit.)

density

0.829 g/mL at 25 °C (lit.)

density

0.838 g/mL at 25 °C (lit.)

density

0.859 g/mL at 25 °C (lit.)

form

liquid

form

liquid

form

liquid

form

liquid

bp

56-57 °C/8 mmHg (lit.)

bp

85-87 °C/10 mmHg (lit.)

bp

79-80 °C/60 mmHg (lit.)

bp

130-133 °C (lit.)

functional group

amine, ether

functional group

amine, ether

functional group

amine, ether

functional group

amine, ether

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pictograms

FlameExclamation mark
GHS02,GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

95.0 °F - closed cup

flash_point_c

35 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
BCCD4190
BCBW4988
BCBR2521V

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U. Widmer
Synthesis, 135-135 (1983)
William B Mathews et al.
Journal of nuclear medicine : official publication, Society of Nuclear Medicine, 46(10), 1719-1726 (2005-10-06)
The goal of this study was to synthesize and evaluate in vivo the peroxisome proliferator-activated receptor-gamma (PPARgamma) agonist (11)C-GW7845 ((S)-2-(1-carboxy-2-{4-[2-(5-methyl-2-phenyloxazol-4-yl)ethoxy]phenyl}ethylamino)benzoic acid methyl ester) ((11)C-compound 1). PPARgamma is a member of a family of nuclear receptors that plays a central role
E Mohacsi et al.
Journal of medicinal chemistry, 25(10), 1264-1266 (1982-10-01)
3-O-tert-Butylmorphine (5) was prepared from 6-O-acetylmorphine (3) via alkylation with N,N-dimethylformamide di-tert-butyl acetal, followed by hydrolytic removal of the 3-(dimethylamino)-2-propenoate group. The same process was used to prepare the tert-butyl ether of levorphanol (6), (-)-3-tert-butoxy-N-methylmorphinan (8). Both 5 and 8
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Global Trade Item Number

SKUGTIN
40263-10ML-F04061837014994
40263-50ML-F04061831985931

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