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Heavily fluorinated carbohydrates as enzyme substrates: oxidation of tetrafluorinated galactose by galactose oxidase.

Chemical communications (Cambridge, England) (2011-09-15)
Avgousta Ioannou, Elena Cini, Roxana S Timofte, Sabine L Flitsch, Nicholas J Turner, Bruno Linclau
ABSTRAKT

Galactose oxidase (GOase) was shown to oxidise several C2/C3 fluorinated galactose analogues. Interestingly, the enzyme was able to distinguish between the 2,3-tetrafluorinated galactose and its epimeric glucose analogue, and this represents the first reported biotransformation of a heavily fluorinated sugar.

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Sigma-Aldrich
Galactose Oxidase from Dactylium dendroides, lyophilized powder, ≥3,000 units/g solid
Sigma-Aldrich
Galactose Oxidase from Dactylium dendroides, ≥30 units/mg solid