88561

2,2′-Thiodiethanol

purum, ≥95.0% (GC)

• Synonim(y): 2,2′-Thiobis(ethanol), Bis(2-hydroxyethyl) sulfide, Thiodiethylene glycol, Thiodiglycol
• Wzór liniowy: S(CH₂CH₂OH)₂
• Numer CAS: 111-48-8
• Masa cząsteczkowa: 122.19
• UNSPSC Code: 12352100
• NACRES: NA.22
• PubChem Substance ID: 329769662
• EC Number: 203-874-3
• Beilstein/REAXYS Number: 1236325
• MDL number: MFCD00002910
• Assay: ≥95.0% (GC)
• Form: liquid

Właściwości

• grade: purum
• Quality Segment: 100
• assay: ≥95.0% (GC)
• form: liquid
• refractive index: n20/D 1.521, n20/D 1.5215 (lit.)
• bp: 164-166 °C/20 mmHg (lit.)
• mp: −16 °C (lit.)
• density: 1.221 g/mL at 25 °C (lit.)
• functional group: hydroxyl, thioether
• SMILES string: OCCSCCO
• InChI: 1S/C4H10O2S/c5-1-3-7-4-2-6/h5-6H,1-4H2
• InChI key: YODZTKMDCQEPHD-UHFFFAOYSA-N

Opis

Application

2,2′-Thiodiethanol is used in the preparation of a wide range of gold complexes, which include Au(I) based catalysts such as chloro(triphenylphosphine)gold(I) [Au(PPh₃)Cl], chloro(dimethyl sulfide)gold(I) [Au(SMe₂)Cl] and chloro[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]gold(I) [IPrAuCl]. It can also be used to build calixarene frameworks.

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Informacja o środkach bezpieczeństwa

• pictograms: GHS07
• signalword: Warning
• hcodes: H319
• pcodes: P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2
• Klasa składowania: 10 - Combustible liquids
• wgk: WGK 1
• ppe: Eyeshields, Gloves, type ABEK (EN14387) respirator filter
• flash_point_f: 329.0 °F - Pensky-Martens closed cup
• flash_point_c: 165 °C - Pensky-Martens closed cup