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Acetic anhydride

ACS reagent grade, ≥98.0%, liquid

Synonim(y):

Acetanhydride, Acetic acid anhydride, Acetyl acetate, Acetyl anhydride, Ethanoic anhydride

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Informacje o tej pozycji

Wzór liniowy:
(CH3CO)2O
Numer CAS:
Masa cząsteczkowa:
102.09
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
203-564-8
MDL number:
Beilstein/REAXYS Number:
385737
Assay:
≥98.0%
Form:
liquid
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Nazwa produktu

Acetic anhydride, ACS reagent, ≥98.0%

grade

ACS reagent

Quality Segment

vapor density

3.5 (vs air)

vapor pressure

10 mmHg ( 36 °C), 4 mmHg ( 20 °C)

assay

≥98.0%

form

liquid

autoignition temp.

629 °F

expl. lim.

10.3 %

impurities

MnO4- reducers, passes test

evapn. residue

≤0.003%

refractive index

n20/D 1.390 (lit.)

bp

138-140 °C (lit.)

mp

−73 °C (lit.)

solubility

H2O: slightly soluble

density

1.08 g/mL (lit.)

anion traces

chloride (Cl-): ≤5 ppm, phosphate (PO43-): ≤0.001%, sulfate (SO42-): ≤5 ppm

cation traces

Fe: ≤5 ppm, heavy metals: ≤2 ppm

functional group

anhydride, ester

SMILES string

CC(=O)OC(C)=O

InChI

1S/C4H6O3/c1-3(5)7-4(2)6/h1-2H3

InChI key

WFDIJRYMOXRFFG-UHFFFAOYSA-N

General description

Acetic anhydride is an organic solvent. On dissolution in water it undergoes solvolysis to afford acetic acid. It is widely employed for the acetylation of various alcohols. Wacher process (starting reagent + a ketene) and Knapsack process (starting reagent = acetaldehyde) have been reported for the industrial preparation of acetic anhydride.

Application

Acetic anhydride has been used as one of the reaction components in the preparation of:
  • 2-acetylamino-5-aminobenzenesulfonic acid
  • 3,3′-bis(sulfonato)-4,4′-bis(chloroacetamido)azobenzene (BSBCA)[1]
  • 10-acetoxy-9-nitro-octadecanoic acid, allyl ester[2]
  • 9-nitro-oleic acid[2]
It may be used for acetylation of anisole over HBEA zeolite in a batch reactor.
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Ta pozycja
33214-M91204539996
assay

≥98.0%

assay

≥99% (GC)

assay

≥99.0% (GC)

assay

99.5%

Quality Level

200

Quality Level

100

Quality Level

100

Quality Level

200

solubility

H2O: slightly soluble

solubility

-

solubility

H2O: slightly soluble

solubility

water: slightly soluble

density

1.08 g/mL (lit.)

density

1.08 g/mL (lit.)

density

1.08 g/mL (lit.)

density

1.08 g/mL (lit.)

bp

138-140 °C (lit.)

bp

138-140 °C (lit.)

bp

138-140 °C (lit.)

bp

138-140 °C (lit.)

refractive index

n20/D 1.390 (lit.)

refractive index

n20/D 1.390 (lit.)

refractive index

n20/D 1.390 (lit.)

refractive index

n20/D 1.390 (lit.)


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signalword

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B

Klasa składowania

3 - Flammable liquids

flash_point_f

120.2 °F - closed cup

flash_point_c

49 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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108-24-7

CAS No.


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Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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