07033

N,N-Bis-((S)-1-phenylethyl)dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine

≥99.0%

• Synonim(y): (S,S)-N-(5,7-Diox-6-phosphadibenzo[a,c]cyclohepten-6-yl)bis(1-phenylethyl)amine, O,O′-(2,2′-Biphenyldiyl) N,N-bis[(S)-1-phenylethyl]phosphoramidite, BIPOL-A1(S)
• Wzór empiryczny (zapis Hilla): C₂₈H₂₆NO₂P
• Numer CAS: 376355-58-7
• Masa cząsteczkowa: 439.49
• NACRES: NA.22
• PubChem Substance ID: 329748328
• UNSPSC Code: 12352005
• MDL number: MFCD08277033
• Assay: ≥99.0%
• Form: powder

Właściwości

• Quality Level: 100
• assay: ≥99.0%
• form: powder
• optical activity: [α]/D -250±10°, c = 1 in toluene
• reaction suitability: reaction type: click chemistry
• mp: 99-102 °C
• SMILES string: C[C@H](N([C@@H](C)c1ccccc1)P2Oc3ccccc3-c4ccccc4O2)c5ccccc5
• InChI: 1S/C28H26NO2P/c1-21(23-13-5-3-6-14-23)29(22(2)24-15-7-4-8-16-24)32-30-27-19-11-9-17-25(27)26-18-10-12-20-28(26)31-32/h3-22H,1-2H3
• InChI key: JISGHECLGYELKD-UHFFFAOYSA-N

Opis

Application

N,N-Bis-((S)-1-phenylethyl)dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine can be used:

• In the iridium catalyzed allylic arylation.
• To prepare a copper complex (Cu₂X₂L₃), which is used to detect the transmetalation intermediates in asymmetric addition reactions using ZnEt₂.

Ta strona może zawierać tekst przetłumaczony maszynowo.

Informacja o środkach bezpieczeństwa

• Klasa składowania: 11 - Combustible Solids
• wgk: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Gloves, type N95 (US)