808024

(S,R,R)-Elenor Amination Reagent

• Synonim(y): 3H-3a,6-Methano-2,1-benzisothiazole-1(4H)-carboxamide, tetrahydro-N-hydroxy-8,8-dimethyl-, 2,2-dioxide, (3aS,6R,7aR)-
• Wzór empiryczny (zapis Hilla): C₁₁H₁₈N₂O₄S
• Numer CAS: 139331-02-5
• Masa cząsteczkowa: 274.34
• MDL number: MFCD29059839
• UNSPSC Code: 12352000
• PubChem Substance ID: 329769052
• NACRES: NA.22

Właściwości

• SMILES string: O=C(N1S(C[C@]2(C3(C)C)CC[C@]3([H])C[C@@]12[H])(=O)=O)NO
• InChI: 1S/C11H18N2O4S/c1-10(2)7-3-4-11(10)6-18(16,17)13(8(11)5-7)9(14)12-15/h7-8,15H,3-6H2,1-2H3,(H,12,14)/t7-,8-,11-/m1/s1
• InChI key: FYSORZDAOUCPGD-SOCHQFKDSA-N
• form: powder
• storage temp.: 2-8°C
• Quality Level: 100

Opis

Application

The following hydroxyamide is a chiral electrophilic nitroso reagent for the transfer of nitrogen to enol ethers. This methology was reported by the Read de Alaniz Group, is a mild approach that can be performed at room temperature and in the presence of air.

Other Notes

Asymmetric Electrophilic α-Amination of Silyl Enol Ether Derivatives via the Nitrosocarbonyl Hetero-ene Reaction

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Informacja o środkach bezpieczeństwa

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319,H335
• pcodes: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Klasa składowania: 11 - Combustible Solids
• wgk: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable