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RuPhos Pd G4

95%, powder

Synonim(y):

[Dicyclohexyl(2′,6′-diisopropoxy-2-biphenylyl)phosphine-κP](methanesulfonatato-κO)[2′-(methylamino-κN)-2-biphenylyl-κC2]palladium

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Rozmiar/SKUDostępnośćCena netto
250 mg
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245,00 zł
1 g
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921,00 zł
5 g
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3060,00 zł

Informacje o tej pozycji

Wzór empiryczny (zapis Hilla):
C44H58NO5PPdS
Numer CAS:
Masa cząsteczkowa:
850.39
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22

245,00 zł


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Nazwa produktu

RuPhos Pd G4,

Quality Segment

product line

Buchwald precatalyst Generation 4

assay

95%

form

powder

feature

generation 4

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Cross Couplings

mp

240 °C

functional group

phosphine

SMILES string

CC(OC1=CC=CC(OC(C)C)=C1C2=C([P+](C3CCCCC3)([Pd-2]4(OS(C)(=O)=O)C(C=CC=C5)=C5C6=C([NH+]4C)C=CC=C6)C7CCCCC7)C=CC=C2)C

InChI

1S/C30H43O2P.C13H12N.CH4O3S.Pd/c1-22(2)31-27-19-13-20-28(32-23(3)4)30(27)26-18-11-12-21-29(26)33(24-14-7-5-8-15-24)25-16-9-6-10-17-25;1-14-13-10-6-5-9-12(13)11-7-3-2-4-8-11;1-5(2,3)4;/h11-13,18-25H,5-10,14-17H2,1-4H3;2-7,9-10,14H,1H3;1H3,(H,2,3,4);/q;;;+1/p-1

InChI key

FDRWYHUTZOCVSQ-UHFFFAOYSA-M

Application

A powerful ligand for classic cross-coupling reactions combined with the Buchwald Fourth Generation Palladacycle. Bench stable, soluble in most organic solvents.
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description

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description

-

description

98%

description

-

assay

95%

assay

-

assay

98%

assay

-

reaction suitability

core: palladium, reaction type: Sonogashira Coupling, reaction type: Suzuki-Miyaura Coupling, reaction type: Stille Coupling, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: catalyst
reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Negishi Coupling, reaction type: Hiyama Coupling

reaction suitability

reaction type: Suzuki-Miyaura Coupling, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reagent type: catalyst, reaction type: Stille Coupling, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Heck Reaction, reaction type: Sonogashira Coupling

reaction suitability

reaction type: Suzuki-Miyaura Coupling, core: palladium, reaction type: Sonogashira Coupling, reaction type: Heck Reaction, reaction type: Stille Coupling, reaction type: Negishi Coupling, reagent type: catalyst
reaction type: Cross Couplings, reaction type: Hiyama Coupling, reaction type: Buchwald-Hartwig Cross Coupling Reaction

reaction suitability

core: palladium, reaction type: Suzuki-Miyaura Coupling, reaction type: Stille Coupling, reagent type: catalyst
reaction type: Cross Couplings, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Sonogashira Coupling, reaction type: Hiyama Coupling, reaction type: Negishi Coupling

functional group

phosphine

functional group

-

functional group

phosphine

functional group

phosphine

form

powder

form

solid

form

solid

form

solid

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

mp

240 °C

mp

-

mp

188-196 °C (decomposition)

mp

195-197 °C


Klasa składowania

11 - Combustible Solids

Co się dzieje?

WGK 3

Temperatura zapłonu (°F)

Not applicable

Temperatura zapłonu (°C)

Not applicable



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Certyfikaty analizy (CoA)

Lot/Batch Number

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Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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