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775797
Isopropylmagnesium bromide solution
0.75 M in THF
Synonim(y):
1-Methylethylmagnesium bromide, 2-Propylmagnesium bromide, iso-Propylmagnesium bromide, Bromoisopropylmagnesium
Wybierz wielkość
| Rozmiar/SKU | Dostępność | Cena netto |
|---|---|---|
100 mL | Skontaktuj się z Obsługą Klienta, aby uzyskać informacje na temat dostępności | 419,00 zł |
4 x 25 mL | Skontaktuj się z Obsługą Klienta, aby uzyskać informacje na temat dostępności | 482,00 zł |
800 mL | Skontaktuj się z Obsługą Klienta, aby uzyskać informacje na temat dostępności | 2410,00 zł |
Informacje o tej pozycji
419,00 zł
form
solution
Quality Segment
reaction suitability
reaction type: Grignard Reaction
packaging
Sure/Seal™ of
concentration
0.75 M in THF
density
0.982 g/mL at 25 °C
storage temp.
2-8°C
SMILES string
CC(C)[Mg]Br
InChI
1S/C3H7.BrH.Mg/c1-3-2;;/h3H,1-2H3;1H;/q;;+1/p-1
InChI key
UCJIVFREPMUZDC-UHFFFAOYSA-M
Application
- Preparation of isopropylmagnesium bromide solutions: In this study, various concentrations of isopropylmagnesium bromide solutions were prepared, detailing their stability and reactivity for use in palladium-catalyzed cross-coupling reactions and other synthetic applications (Vulović et al., 2017).
- Reductive coupling of amides: This research discusses the reductive functionalization of tertiary amides using isopropylmagnesium bromide, providing a novel method for amine synthesis, which is crucial for pharmaceutical chemistry (Xie and Dixon, 2017).
- Synthesis of 1, 2, 3-triazoles: The study explores the use of isopropylmagnesium bromide in the synthesis of 1, 2, 3-triazoles through Grignard reactions, highlighting its role in protecting azides during the reaction process (Namioka et al., 2023).
- Disposable cartridge concept for Grignard reagents: This paper introduces a novel disposable cartridge for the on-demand synthesis of Grignard reagents, including isopropylmagnesium bromide, enhancing the safety and scalability of Grignard reactions (Berton et al., 2020).
Packaging
Legal Information
1 of 1
Ta pozycja | |||
|---|---|---|---|
| description 0.75 M in THF | description 2.9 M in 2-methyltetrahydrofuran | description 0.5 M in THF | description 1.4 M in THF: toluene (1:3) |
| reaction suitability reaction type: Grignard Reaction | reaction suitability reaction type: Grignard Reaction | reaction suitability reaction type: Grignard Reaction | reaction suitability reaction type: Grignard Reaction |
| concentration 0.75 M in THF | concentration 40 % (w/w), 2.9 M in 2-methyltetrahydrofuran | concentration 0.5 M in THF | concentration 1.4 M in THF: toluene (1:3) |
| Quality Level 100 | Quality Level 100 | Quality Level 100 | Quality Level 200 |
| density 0.982 g/mL at 25 °C | density 1.112 g/mL at 25 °C | density 0.935 g/mL at 25 °C | density 1.018 g/mL at 25 °C |
| storage temp. 2-8°C | storage temp. - | storage temp. - | storage temp. - |
| form solution | form liquid | form - | form - |
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Słowo ostrzegawcze
Danger
Kody zagrożeń
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react. 1
Narządy docelowe
Central nervous system, Respiratory system
supp_hazards
Klasa składowania
4.3 - Hazardous materials which set free flammable gases upon contact with water
Temperatura zapłonu (°F)
-22.0 °F - closed cup
Temperatura zapłonu (°C)
-30 °C - closed cup
Wykazy regulacyjne
Wykazy regulacyjne dotyczą głównie produktów chemicznych. Można w nich podawać ograniczoną liczbę informacji na temat produktów niechemicznych. Brak wpisu oznacza, że żaden ze składników nie znajduje się w wykazie. Użytkownik odpowiada za zagwarantowanie bezpiecznego i zgodnego z prawem stosowania produktu.
109-99-9 + 920-39-8
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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