734527

Tetrakis(pyridine)copper(II) triflate

95%, crystals

• Synonim(y): [Cu(OTf)₂(py)₄], Cu(pyridine)₄(OTf)₂, Tetrakis(pyridine)copper(II) bis(trifluoromethanesulfonate)
• Wzór empiryczny (zapis Hilla): C₂₂H₂₀CuF₆N₄O₆S₂
• Numer CAS: 113110-58-0
• Masa cząsteczkowa: 678.08
• MDL number: MFCD19105629
• UNSPSC Code: 12161600
• PubChem Substance ID: 329764907
• NACRES: NA.22

Właściwości

• Nazwa produktu: Tetrakis(pyridine)copper(II) triflate, 95%
• Quality Segment: 100
• assay: 95%
• form: crystals
• reaction suitability: core: copper, reagent type: catalyst
• mp: 190-194 °C
• storage temp.: −20°C
• SMILES string: c1ccncc1.c2ccncc2.c3ccncc3.c4ccncc4.FC(F)(F)S(=O)(=O)O[Cu]OS(=O)(=O)C(F)(F)F
• InChI: 1S/4C5H5N.2CHF3O3S.Cu/c4*1-2-4-6-5-3-1;2*2-1(3,4)8(5,6)7;/h4*1-5H;2*(H,5,6,7);/q;;;;;;+2/p-2
• InChI key: DOUMBTAZXRQKGF-UHFFFAOYSA-L

Opis

Application

Tetrakis(pyridine)copper(II) triflate [Cu(OTf)₂(py)₄] is a general copper-based catalyst. It is commonly used to catalyze copper-mediated radiofluorination of arenes and heteroarene. It is also employed in C(sp³)-H functionalization/cyclisation of 2-amino-N,N-dialkylbenzamides to synthesize 2,3-disubstituted-4(3H)-quinazolinones.

Tetrakis(pyridine)copper(II) triflate can be used to catalyze:

• Intra and intermolecular aziridination of allylic carbamates and styrenes.
• ¹⁸F-fluorination of aryl boronic esters to generate fluroarenes applicable as radiotracers.
• Nucleophilic radiobromination of aryl borons with a radiobromide ion applicable in the preparation of radiobrominated pharmaceuticals.

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Informacja o środkach bezpieczeństwa

• Piktogramy: GHS05
• Słowo ostrzegawcze: Danger
• Kody zagrożeń: H314
• Ostrzeżenia: P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363
• Hazard Classifications: Skin Corr. 1B
• Klasa składowania: 8A - Combustible corrosive hazardous materials
• Co się dzieje?: WGK 3
• Temperatura zapłonu (°F): Not applicable
• Temperatura zapłonu (°C): Not applicable