688096

Tris[2-phenylpyridinato-C²,N]iridium(III)

97%

• Synonim(y): Ir(ppy)₃, Iridium, tris[2-(2-pyridinyl-κN)phenyl-κC]
• Wzór empiryczny (zapis Hilla): C₃₃H₂₄IrN₃
• Numer CAS: 94928-86-6
• Masa cząsteczkowa: 654.78
• Numer MDL: MFCD12022527
• Kod UNSPSC: 12352103
• Identyfikator substancji w PubChem: 329760833
• NACRES: NA.23

Właściwości

• opis: fac-Tris[2-phenylpyridinato-C₂,N]iridium(III)
• Próba: 97%
• Postać: powder
• przydatność reakcji: core: iridium; reaction type: Photocatalysis; reagent type: catalyst
• aktywacja fotokatalizatora: 425 nm
• fluorescencja: λ_ex 340 nm; λ_em 512 nm in chloroform
• Energia orbitalna: HOMO 5.6 eV ; LUMO 3 eV
• Wydajność urządzenia OLED: ITO/HMPD/TAZ:Ir(ppy)₃ (7%)/Alq₃/Al:Li;
  • Color: green
  • Max. Luminance: 4000 Cd/m²
  • Max. EQE: 15 %
  ; ITO/NPD/CBP:Ir(ppy)₃ (6%)/Alq₃/Mg:Ag;
  • Color: green
  • Max. Luminance: 100000 Cd/m²
  • Max. EQE: 8 %
  • Turn-On Voltage: 4.3 V
  ; ITO/NPD/TCTA/BCPO:Ir(ppy)₃ (7-8%)/BCP/Alq₃/LiF/Al;
  • Color: green
  • Max. Luminance: 207839 Cd/m²
  • Max. EQE: 21.6 %
  • Turn-On Voltage: 2.1 V
  ; ITO/TCTA/Ir(ppy)₃/Bphen/LiF/Al;
  • Color: green
  • Max. Luminance: 300000 Cd/m²
  • Max. EQE: 19 %
  • Turn-On Voltage: 2.6 V
• ciąg SMILES: c1ccc(nc1)-c2ccccc2[Ir](c3ccccc3-c4ccccn4)c5ccccc5-c6ccccn6
• InChI: 1S/3C11H8N.Ir/c3*1-2-6-10(7-3-1)11-8-4-5-9-12-11;/h3*1-6,8-9H;
• Klucz InChI: QKBWDYLFYVXTGE-UHFFFAOYSA-N

Opis

Opis ogólny

Tris-(2-phenylpyridine) iridium [Ir(ppy)₃] is a heavy metal complex. [Ir(ppy)₃] is the most frequently used precursor molecule for the synthesis of electro-phosphorescent materials, which are then used in organic light emitting diodes (OLEDs). It provides green-color emission and high phosphorescence quantum yield close to unity.

Zastosowanie

Learn More at the Professor and Product Portal of Professor Corey Stephenson.

Put to elegant use by Stephenson for the reduction of alkyl, alkenyl and aryl iodides in the presence of visible light. Intramolecular reductive cyclizations were also achieved with this catalyst.

Engaging unactivated alkyl, alkenyl and aryl iodides in visible-light-mediated free radical reactions

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Informacja o środkach bezpieczeństwa

• Kod klasy składowania: 11 - Combustible Solids
• Klasa zagrożenia wodnego (WGK): WGK 3
• Temperatura zapłonu (°F): Not applicable
• Temperatura zapłonu (°C): Not applicable
• Środki ochrony indywidualnej: dust mask type N95 (US), Eyeshields, Gloves