680990

1,1′-Bis[(2R,5R)-2,5-diethylphospholano]ferrocene

• Synonim(y): R,R-Et-Ferrocelane^™
• Wzór empiryczny (zapis Hilla): C₂₆H₄₀FeP₂
• Numer CAS: 147762-89-8
• Masa cząsteczkowa: 470.39
• MDL number: MFCD09265149
• UNSPSC Code: 12352005
• PubChem Substance ID: 24885607
• NACRES: NA.22

Właściwości

• form: solid
• Quality Segment: 100
• optical activity: [α]20/D +380°, c = 1 in chloroform
• mp: 85-91 °C
• functional group: phosphine
• SMILES string: C[Fe]C.CC[C@@H]1CC[C@@H](CC)P1[C@@H]2CCCC2.CC[C@@H]3CC[C@@H](CC)P3[C@H]4CCCC4
• InChI: 1S/2C13H25P.2CH3.Fe/c2*1-3-11-9-10-12(4-2)14(11)13-7-5-6-8-13;;;/h2*11-13H,3-10H2,1-2H3;2*1H3;/t2*11-,12-;;;/m11.../s1
• InChI key: CPUKIDAUDCWIRT-QULUYMGFSA-N

Opis

Application

DuPhos and BPE Ligands: Highly Efficient Privileged Ligands

1,1′-Bis[(2R,5R)-2,5-diethylphospholano]ferrocene can be used:

• As a catalyst in the asymmetric hydrogenation reactions of olefins and ketones.
• As a component of a rhodium based precatalyst, applicable in the 2-methylenesuccinamic acid hydrogenation reaction.

Legal Information

Sold in collaboration with Kanata Chemical Technologies Inc. for research purposes only. These compounds were made and sold under license from E.I. du Pont de Nemours and Company, which license does not include the right to use the compounds in producing products for sale in the pharmaceutical field.

Ferrocelane is a trademark of Kanata Chemical Technologies, Inc.

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Informacja o środkach bezpieczeństwa

• Klasa składowania: 11 - Combustible Solids
• Co się dzieje?: WGK 3
• Temperatura zapłonu (°F): Not applicable
• Temperatura zapłonu (°C): Not applicable