678538

(−)-Ipc₂B(allyl)borane solution

1 M in pentane

• Synonim(y): (-)-Ipc₂B(allyl) solution, (−)-B-Allyldiisopinocampheylborane solution
• Wzór liniowy: (C₁₀H₁₇)₂BCH₂CH=CH₂
• Numer CAS: 85116-38-7
• Masa cząsteczkowa: 326.37
• MDL number: MFCD09038448
• UNSPSC Code: 12352002
• PubChem Substance ID: 24885432
• NACRES: NA.22

Właściwości

• optical activity: [α]20/D −35 to ±5°, c = 1
• Quality Segment: 100
• concentration: 1 M in pentane
• bp: 35-36 °C
• density: 0.638 g/mL at 25 °C
• storage temp.: −20°C
• SMILES string: C[C@H]1[C@@H](C[C@@H]2C[C@H]1C2(C)C)B(CC=C)[C@@H]3C[C@@H]4C[C@H]([C@H]3C)C4(C)C
• InChI: 1S/C23H39B/c1-8-9-24(20-12-16-10-18(14(20)2)22(16,4)5)21-13-17-11-19(15(21)3)23(17,6)7/h8,14-21H,1,9-13H2,2-7H3/t14-,15-,16+,17+,18-,19-,20-,21-/m1/s1
• InChI key: ZIXZBDJFGUIKJS-RLEROFIGSA-N

Opis

Application

This allylboration reagent is a convenient, salt-free, stable solution of a chiral allyl borane for asymmetric allylation of aldehydes leading to chiral homoallylic alcohols.

Other Notes

Material may become hazy upon cooler storage, this will not affect use

Under refrigerator storage, these salt-free, Ipc₂B(allyl) reagents do not show any appreciable decrease in selectivity is observed after several months. They exhibit excellent reactivity and reactions can be performed at 5°C, even in water.

Disclaimer

Supply conditions do not apply to the regions and states of Brazil: North, Northeast, Mato Grosso do Sul, Mato Grosso, and Rio Grande do Sul.

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Informacja o środkach bezpieczeństwa

• Piktogramy: GHS02,GHS08,GHS07,GHS09
• Słowo ostrzegawcze: Danger
• Kody zagrożeń: H224,H304,H315,H319,H335,H336,H411
• Ostrzeżenia: P210 - P233 - P273 - P301 + P310 - P331 - P403 + P233
• Hazard Classifications: Aquatic Chronic 2 - Asp. Tox. 1 - Eye Irrit. 2 - Flam. Liq. 1 - Skin Irrit. 2 - STOT SE 3
• Narządy docelowe: Central nervous system, Respiratory system
• Klasa składowania: 3 - Flammable liquids
• Co się dzieje?: WGK 3
• Temperatura zapłonu (°F): -56.2 °F - closed cup
• Temperatura zapłonu (°C): -49 °C - closed cup
• PPE (środki ochrony indywidualnej): Eyeshields, Faceshields, Gloves