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For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf
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577928
Lithium bis(trimethylsilyl)amide solution
1 M in toluene
Synonim(y):
LiHMDS, Hexamethyldisilazane lithium salt
Wybierz wielkość
| Rozmiar/SKU | Dostępność | Cena netto |
|---|---|---|
100 mL | Skontaktuj się z Obsługą Klienta, aby uzyskać informacje na temat dostępności | 328,00 zł |
800 mL | Skontaktuj się z Obsługą Klienta, aby uzyskać informacje na temat dostępności | 1860,00 zł |
Informacje o tej pozycji
328,00 zł
Quality Segment
concentration
1 M in toluene
density
0.860 g/mL at 25 °C
SMILES string
[Li]N([Si](C)(C)C)[Si](C)(C)C
InChI
1S/C6H18NSi2.Li/c1-8(2,3)7-9(4,5)6;/h1-6H3;/q-1;+1
InChI key
YNESATAKKCNGOF-UHFFFAOYSA-N
General description
Application
- In the deprotonation and nucleophilic difluoromethylation reactions.
- To synthesize isoquinoline derivatives by the addition of N-iodosuccinimide (NIS) to the α-benzyl tosylmethyl isocyanides.
- To prepare arylboronic acid pinacol esters by the reaction of aryl fluorides with bis(pinacolato)diboron via palladium-catalyzed cross-coupling reaction.
1 of 1
Ta pozycja | |||
|---|---|---|---|
| description 1 M in toluene | description 1.0 M in hexanes | description 1.5 M in THF | description 99.9% trace metals basis |
| concentration 1 M in toluene | concentration 1.0 M in hexanes | concentration 1.5 M in THF | concentration - |
| Quality Level 200 | Quality Level 100 | Quality Level 100 | Quality Level 200 |
| density 0.860 g/mL at 25 °C | density 0.707 g/mL at 25 °C | density 0.893 g/mL at 25 °C | density 0.860 g/mL at 25 °C (lit.) |
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signalword
Danger
Hazard Classifications
Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Self-heat. 1 - Skin Corr. 1B - STOT RE 2 - STOT SE 3
target_organs
Central nervous system
supp_hazards
Klasa składowania
4.2 - Pyrophoric and self-heating hazardous materials
wgk
WGK 3
flash_point_f
48.0 °F - closed cup
flash_point_c
8.9 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Wykazy regulacyjne
Wykazy regulacyjne dotyczą głównie produktów chemicznych. Można w nich podawać ograniczoną liczbę informacji na temat produktów niechemicznych. Brak wpisu oznacza, że żaden ze składników nie znajduje się w wykazie. Użytkownik odpowiada za zagwarantowanie bezpiecznego i zgodnego z prawem stosowania produktu.
108-88-3
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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