555142

1-Diphenylphosphino-1′-(di-tert-butylphosphino)ferrocene

solid

• Wzór empiryczny (zapis Hilla): C₃₀H₃₆FeP₂
• Numer CAS: 95408-38-1
• Masa cząsteczkowa: 514.40
• UNSPSC Code: 12352005
• PubChem Substance ID: 24879174
• NACRES: NA.22
• MDL number: MFCD03701526

Właściwości

• Nazwa produktu: 1-Diphenylphosphino-1′-(di-tert-butylphosphino)ferrocene,
• form: solid
• Quality Segment: 100
• reaction suitability: reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand; reaction type: Coupling Reactions
• greener alternative product characteristics: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• mp: 75-79 °C (lit.)
• functional group: phosphine
• greener alternative category: Aligned
• SMILES string: [Fe].CC(C)(C)P([C]1[CH][CH][CH][CH]1)C(C)(C)C.[CH]2[CH][CH][C]([CH]2)P(c3ccccc3)c4ccccc4
• InChI: 1S/C17H14P.C13H22P.Fe/c1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;1-12(2,3)14(13(4,5)6)11-9-7-8-10-11;/h1-14H;7-10H,1-6H3;
• InChI key: GQIMIFFIUZZVMJ-UHFFFAOYSA-N

Opis

General description

We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives. This product falls under category 12 PAP and aligns with the Green Chemistry Principle of Catalysis. It is an unsymmetric diphosphine ligand for asymmetric catalysis, combining different phosphine environments to provide enhanced selectivity in metal-catalyzed reactions. Click here for more information.

Application

• Catalyst in microwave-assisted preparation of aryl-alkyl ethers via palladium-catalyzed Hiyama coupling of alkoxysilanes with aryl bromides or aryl chlorides
• Ligand for catalytic isomerization of methylbutenenitrile via nickel systems
• Ligand for ruthenium alkylidene complexes for catalysis of metathesis reactions and catalytic norbornene polymerization

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Informacja o środkach bezpieczeństwa

• Klasa składowania: 11 - Combustible Solids
• Co się dzieje?: WGK 3
• Temperatura zapłonu (°F): Not applicable
• Temperatura zapłonu (°C): Not applicable
• PPE (środki ochrony indywidualnej): Eyeshields, Gloves, type N95 (US)