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570958

Tri-tert-butylphosphine

98%

Synonim(y):

P(t-Bu)3

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Rozmiar/SKUDostępnośćCena netto
1 g
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618,00 zł
5 g
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2340,00 zł
10 g
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3610,00 zł

Informacje o tej pozycji

Wzór liniowy:
[(CH3)3C]3P
Numer CAS:
Masa cząsteczkowa:
202.32
UNSPSC Code:
12352128
NACRES:
NA.22
PubChem Substance ID:
EC Number:
237-266-4
Beilstein/REAXYS Number:
1738613
MDL number:

618,00 zł


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Quality Segment

assay

98%

reaction suitability

reaction type: Cross Couplings, reagent type: ligand
reaction type: Addition Reactions, reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: ligand
reaction type: Heck Reaction, reagent type: ligand
reaction type: Negishi Coupling, reagent type: ligand
reaction type: Sonogashira Coupling, reagent type: ligand
reaction type: Stille Coupling, reagent type: ligand
reaction type: Suzuki-Miyaura Coupling

bp

102-103 °C/13 mmHg (lit.)

mp

30-35 °C (lit.)

density

0.834 g/mL at 20 °C (lit.)

functional group

phosphine

SMILES string

CC(C)(C)P(C(C)(C)C)C(C)(C)C

InChI

1S/C12H27P/c1-10(2,3)13(11(4,5)6)12(7,8)9/h1-9H3

InChI key

BWHDROKFUHTORW-UHFFFAOYSA-N

Application

Preferred ligand in the palladium-catalyzed coupling of arylboronic acids with phenyliodonium ylides of hydroxyquinones. Also used with Pd2(dba)3 for the α-arylation of trimethylsilyl enol ethers with aryl halides.
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Ta pozycja
901438655325901441
description

98%

description

1.0 M in THF

description

1.0 M in toluene

description

1.0 M in 2-methyltetrahydrofuran

reaction suitability

reagent type: ligand
reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
reaction type: Heck Reaction, reaction type: Cross Couplings, reagent type: ligand
reaction type: Sonogashira Coupling, reagent type: ligand
reaction type: Negishi Coupling, reagent type: ligand
reaction type: Addition Reactions, reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: ligand
reaction type: Stille Coupling

reaction suitability

reagent type: ligand
reaction type: Addition Reactions, reagent type: ligand
reaction type: Stille Coupling, reaction type: Cross Couplings, reagent type: ligand
reaction type: Sonogashira Coupling, reagent type: ligand
reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: ligand
reaction type: Heck Reaction, reagent type: ligand
reaction type: Negishi Coupling

reaction suitability

reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: ligand
reaction type: Addition Reactions, reagent type: ligand
reaction type: Negishi Coupling, reagent type: ligand
reaction type: Stille Coupling, reagent type: ligand
reaction type: Heck Reaction, reagent type: ligand
reaction type: Sonogashira Coupling, reagent type: ligand
reaction type: Suzuki-Miyaura Coupling

reaction suitability

reagent type: ligand
reaction type: Sonogashira Coupling, reagent type: ligand
reaction type: Addition Reactions, reagent type: ligand
reaction type: Stille Coupling, reagent type: ligand
reaction type: Heck Reaction, reagent type: ligand
reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: ligand
reaction type: Negishi Coupling

assay

98%

assay

-

assay

-

assay

-

functional group

phosphine

functional group

phosphine

functional group

phosphine

functional group

phosphine

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

bp

102-103 °C/13 mmHg (lit.)

bp

-

bp

-

bp

-

density

0.834 g/mL at 20 °C (lit.)

density

0.878 g/mL

density

0.861 g/mL at 25 °C

density

0.853 g/mL


Piktogramy

FlameCorrosion

Słowo ostrzegawcze

Danger

Kody zagrożeń

Hazard Classifications

Eye Dam. 1 - Pyr. Sol. 1 - Skin Corr. 1B

Klasa składowania

4.2 - Pyrophoric and self-heating hazardous materials

Co się dzieje?

WGK 3

Temperatura zapłonu (°F)

1.4 °F

Temperatura zapłonu (°C)

-17 °C

PPE (środki ochrony indywidualnej)

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges



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Certyfikaty analizy (CoA)

Lot/Batch Number

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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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