Methyl cyanoformate is an organic compound that is commonly used as a source of the methoxycarbonyl group in organic synthesis. It is most frequently used as a reagent to synthesize regioselective β-keto esters via C-acylation of lithium enolates. In comparison with more traditional reagents such as acyl halides, anhydrides, and carbon dioxide, it is regarded as a superior acylating agent.
Journal of medicinal chemistry, 36(23), 3503-3510 (1993-11-12)
A variety of isosteres of the DNA polymerase inhibitor aphidicolin were synthesized as potential antiherpes agents. Modeling studies indicated that the bicyclooctane C, D rings of aphidicolin could be replaced by an aromatic moiety while maintaining the spatial arrangement of
Tetrahedron Letters, 34, 8553-8553 (1993)
Tetrahedron, 48, 7979-7979 (1992)
Aldrichimica Acta, 20, 53-53 (1987)
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