254142

Bismuth(III) chloride

99.99% trace metals basis

• Synonim(y): Bismuth trichloride, Trichlorobismuth
• Wzór liniowy: BiCl₃
• Numer CAS: 7787-60-2
• Masa cząsteczkowa: 315.34
• NACRES: NA.23
• PubChem Substance ID: 24855360
• UNSPSC Code: 12352302
• EC Number: 232-123-2
• MDL number: MFCD00003461
• Assay: 99.99% trace metals basis
• Form: solid

Właściwości

• Quality Segment: 100
• assay: 99.99% trace metals basis
• form: solid
• reaction suitability: core: bismuth, reagent type: catalyst
• greener alternative product characteristics: Design for Energy Efficiency; Design for Energy Efficiency; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product, Greener Alternative Product
• impurities: ≤150.0 ppm Trace Metal Analysis
• bp: 447 °C (lit.)
• mp: 230-232 °C (lit.)
• application(s): material synthesis precursor; perovskite solar cells
• greener alternative category: Enabling, Enabling
• SMILES string: Cl[Bi](Cl)Cl
• InChI: 1S/Bi.3ClH/h;3*1H/q+3;;;/p-3
• InChI key: JHXKRIRFYBPWGE-UHFFFAOYSA-K

Opis

General description

Bismuth(III) chloride is a Lewis acid catalyst and a common source of Bi³⁺ ions used in various organic transformations and synthesis of bismuth nanomaterials.

We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives. This is an enabling product and can be used as a precursor to make perovskite oxides, which promote thermoelectric heat-to-electricity conversion, improving energy efficiency. Click here for more information.

Application

Bismuth(III) chloride can be used:

• As a precursor to prepare polyaniline and bismuth(III) telluride nanohybrids with high thermoelectric performance.
• As a starting material to synthesize visible light absorbing double perovskite semiconductors, such as Cs₂AgBiBr₆ and Cs₂AgBiCl₆, eco-friendly alternative to the lead halide perovskites.
• To form a protective layer on anode materials.

It can also be used as an efficient catalyst for green synthesis of:

• Chalcones by Claisen–Schmidt reaction under solvent-free conditions.
• One-pot three-component synthesis of Propargylamines.
• Coumarins via ultrasound‐assisted Pechmann condensation of phenols with β‐ketoesters.

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Informacja o środkach bezpieczeństwa

• Piktogramy: GHS07
• Słowo ostrzegawcze: Warning
• Kody zagrożeń: H315,H319
• Ostrzeżenia: P264 - P280 - P302 + P352 - P305 + P351 + P338 - P332 + P313 - P337 + P313
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2
• Klasa składowania: 11 - Combustible Solids
• Co się dzieje?: WGK 2
• Temperatura zapłonu (°F): Not applicable
• Temperatura zapłonu (°C): Not applicable
• PPE (środki ochrony indywidualnej): dust mask type N95 (US), Eyeshields, Gloves