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14694

Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

Synonim(y):

Rhodium(I) tetrafluoroborate 1,5-Cyclooctadiene complex

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Rozmiar/SKUDostępnośćCena netto
100 mg
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576,00 zł

Informacje o tej pozycji

Wzór empiryczny (zapis Hilla):
C16H24BF4Rh
Numer CAS:
Masa cząsteczkowa:
406.07
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
MDL number:

576,00 zł


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composition

carbon content, 45.7-49.0%

Quality Segment

reaction suitability

core: rhodium, reagent type: catalyst

mp

~190 °C (dec.)

SMILES string

[Rh+].F[B-](F)(F)F.C1CC=CCCC=C1.C2CC=CCCC=C2

InChI

1S/2C8H12.BF4.Rh/c2*1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h2*1-2,7-8H,3-6H2;;/q;;-1;+1/b2*2-1-,8-7-;;

InChI key

NBGSCPNNKGVTKU-QMDOQEJBSA-N

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

Other Notes

Rhodium complex employed for preparing cationic COD-Rh complexes with phosphine ligands, e.g. for enantioselective hydrogenation; Hydrosilylation
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683140334987530840
description

-

description

-

description

97%

description

98%

reaction suitability

core: rhodium, reagent type: catalyst

reaction suitability

core: rhodium, reagent type: catalyst

reaction suitability

reagent type: catalyst, core: rhodium

reaction suitability

core: rhodium, reagent type: catalyst

Quality Level

100

Quality Level

100

Quality Level

200

Quality Level

100

mp

~190 °C (dec.)

mp

165 °C (dec.) (lit.)

mp

165 °C (dec.) (lit.)

mp

159 °C (dec. literature value) (lit.)

composition

carbon content, 45.7-49.0%

composition

-

composition

-

composition

-


Piktogramy

Health hazardExclamation mark

Słowo ostrzegawcze

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

Narządy docelowe

Respiratory system

Klasa składowania

4.1B - Flammable solid hazardous materials

WGK

WGK 3

Temperatura zapłonu (°F)

Not applicable

Temperatura zapłonu (°C)

Not applicable

PPE (środki ochrony indywidualnej)

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges



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Certyfikaty analizy (CoA)

Lot/Batch Number

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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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