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Merck

32203

Sigma-Aldrich

二乙醚

≥99.8% (GC), ACS reagent, puriss. p.a., contains BHT as inhibitor, reag. Ph. Eur., reag. ISO, USP/NF

别名:

乙醚, 醚

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About This Item

线性分子式:
(CH3CH2)2O
CAS号:
分子量:
74.12
Beilstein:
1696894
EC號碼:
MDL號碼:
分類程式碼代碼:
12352112
PubChem物質ID:
NACRES:
NA.07

product name

二乙醚, contains BHT as inhibitor, puriss. p.a., ACS reagent, reag. ISO, reag. Ph. Eur., ≥99.8% (GC)

等級

ACS reagent
puriss. p.a.

品質等級

agency

USP/NF
reag. ISO
reag. Ph. Eur.

蒸汽密度

2.6 (vs air)

化驗

≥99.8% (GC)

形狀

liquid

自燃溫度

320 °F

包含

BHT as inhibitor

expl. lim.

36.5 %

雜質

≤0.00003% peroxides (as H2O2)
≤0.00007% adehydes (as HCHO)
≤0.0002% free acid (as CH3COOH)
≤0.001% carbonyl compounds (as CO)
≤0.001% non-volatile matter
≤0.005% acetone (GC)
≤0.02% ethanol (GC)
0.03% water (Karl Fischer)
5-8 ppm BHT (GC)

折射率

n20/D 1.3530 (lit.)

bp

34.6 °C (lit.)

mp

−116 °C (lit.)

密度

0.706 g/mL at 25 °C (lit.)

正離子痕跡

Al: ≤0.5 mg/kg
B: ≤0.02 mg/kg
Ba: ≤0.1 mg/kg
Ca: ≤0.5 mg/kg
Cd: ≤0.05 mg/kg
Co: ≤0.02 mg/kg
Cr: ≤0.02 mg/kg
Cu: ≤0.02 mg/kg
Fe: ≤0.05 mg/kg
Mg: ≤0.1 mg/kg
Mn: ≤0.02 mg/kg
Ni: ≤0.02 mg/kg
Pb: ≤0.05 mg/kg
Sn: ≤0.1 mg/kg
Zn: ≤0.05 mg/kg

SMILES 字串

CCOCC

適合性

passes test for reaction against H2SO4

InChI

1S/C4H10O/c1-3-5-4-2/h3-4H2,1-2H3

InChI 密鑰

RTZKZFJDLAIYFH-UHFFFAOYSA-N

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一般說明

Diethyl ether (DEE) is widely employed as solvent for Grignard synthesis. Its efficacy as solvent for formalin-ether (F-E) sedimentation technique has been studied. It has been reported as a hydroboration solvent. DEE is a promising compression-ignition fuel and its energy density is much higher than ethanol. It is also one of the components in a blend used in diesel fuel. It can also be used as alternative of diesel fuel.

應用

Diethyl ether may be employed as solvent for the oxidation of secondary alcohols into ketones. It may be employed as solvent in the preparation of triblock copolymer of PCL-PEG-PCL, acrylated PCL-PEG-PCL and the pentablock copolymer PAE-PCL-PEG-PCL-PAE [PAE = poly(β-amino ester), PEG = poly(ethylene glycol), PCL = poly(ε-caprolactone)].

其他說明

The article number 32203-4X2.5L will be discontinued. Please order the single bottle 32203-2.5L which is physically identical with the same exact specifications.
The article number 32203-4X2.5L-M will be discontinued. Please order the single bottle 32203-2.5L-M which is physically identical with the same exact specifications.
The article number 32203-6X1L will be discontinued. Please order the single bottle 32203-1L which is physically identical with the same exact specifications.
The article number 32203-6X1L-M will be discontinued. Please order the single bottle 32203-1L-M which is physically identical with the same exact specifications.

象形圖

FlameExclamation mark

訊號詞

Danger

危險聲明

危險分類

Acute Tox. 4 Oral - Flam. Liq. 1 - STOT SE 3

標靶器官

Respiratory system

安全危害

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 1

閃點(°F)

-40.0 °F

閃點(°C)

-40 °C


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其他客户在看

Dai P Huynh et al.
Biomaterials, 29(16), 2527-2534 (2008-03-11)
The concept of this research is using poly(beta-amino ester) (PAE) as a duo-functional group for synthesis of the novel sensitive injectable hydrogel for controlled drug/protein delivery. Firstly, PAE made of 1,4-butanediol diacrylate and 4,4'-trimethylene dipiperidine is used as a pH-sensitive
Diethyl ether (DEE) as a renewable diesel fuel.
Bailey B, et al.
No. 972978. SAE technical paper (1997)
Eagleson M.
Concise Encyclopedia Chemistry, 471-471 (1994)
Oxidation of secondary alcohols in diethyl ether with aqueous chromic acid. Convenient procedure for the preparation of ketones in high epimeric purity.
Brown HC, et al.
The Journal of Organic Chemistry, 36(3), 387-390 (1971)
Tatsuya Yoshino et al.
Organic letters, 14(16), 4290-4292 (2012-08-09)
A highly efficient total synthesis of the 11-membered cyclic aspercyclides A (1) and B (2) has been achieved by chemo- and regioselective intramolecular oxidative C-O bond formation from differently substituted diphenols.

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