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Merck

248614

Sigma-Aldrich

过硫酸铵

Ammonium persulfate

ACS reagent, ≥98.0%

别名:

AP, APS, PER, 过硫酸铵

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About This Item

线性分子式:
(NH4)2S2O8
CAS号:
分子量:
228.20
EC 号:
MDL编号:
UNSPSC代码:
12352300
PubChem化学物质编号:
NACRES:
NA.21
方案:
≥98.0%
等级:
ACS reagent
表单:
chunks or granules
powder or crystals
价格与库存信息目前不能提供

等级

ACS reagent

质量水平

蒸汽密度

7.9 (vs air)

方案

≥98.0%

表单

chunks or granules
powder or crystals

反应适用性

reagent type: oxidant

杂质

≤0.005% insolubles
≤0.04 meq/g Titr. acid

灼烧残渣

≤0.05%

pH值(酸碱度)

1-2 (25 °C, 228 g/L)

痕量阴离子

Cl- and ClO4-: ≤0.001%

痕量阳离子

Fe: ≤0.001%
Mn: ≤0.5 ppm
heavy metals (as Pb): ≤0.005%

SMILES字符串

N.N.OS(=O)(=O)OOS(O)(=O)=O

InChI

1S/2H3N.H2O8S2/c;;1-9(2,3)7-8-10(4,5)6/h2*1H3;(H,1,2,3)(H,4,5,6)

InChI key

ROOXNKNUYICQNP-UHFFFAOYSA-N

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一般描述

过硫酸铵是一种很容易获得的氧化剂,用于各种化学转化,也被用作化学工业中的漂白剂。

应用

丙烯酰胺凝胶聚合催化剂。
过硫酸铵可用作氧化剂,用于以下物质的无溶剂氧化:
  • 伯醇和仲醇在水介质中转化为相应的羰基化合物。
  • 硫醇转化为二硫化物。
它还可用作引发剂,引发丙烯腈与衣康酸的共聚反应。

警示用语:

Danger

危险分类

Acute Tox. 4 Oral - Eye Irrit. 2 - Ox. Sol. 3 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

靶器官

Respiratory system

储存分类代码

5.1B - Oxidizing hazardous materials

WGK

WGK 1

闪点(°F)

Not applicable

闪点(°C)

Not applicable


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Slide 1 of 1

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S Pino et al.
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Synthetic Metals, 140(1), 15-21 (2004)
Solid state deoximation with ammonium persulfate-silica gel: Regeneration of carbonyl compounds using microwaves.
Varma RS and Meshram HM.
Tetrahedron Letters, 38(31), 5427-5428 (1997)
J M Brewer
Science (New York, N.Y.), 156(3772), 256-257 (1967-04-14)
Ammonium persulfate, a common polymerizing agent for acrylamide gels, can inactivate yeast enolase and produce increased electrophoretic heterogeneity during disc electrophoresis in gels containing 8M urea. The use of riboflavin and light for polymerization or thioglycolate for removal of the

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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