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Merck

207802

Sigma-Aldrich

重铬酸钾

ACS reagent, ≥99.0%

别名:

红矾钾

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About This Item

线性分子式:
K2Cr2O7
CAS号:
分子量:
294.18
EC 号:
MDL编号:
UNSPSC代码:
12352302
PubChem化学物质编号:
NACRES:
NB.24
价格与库存信息目前不能提供

等级

ACS reagent

方案

≥99.0%

表单

crystals

反应适用性

reagent type: oxidant

杂质

≤0.005% insolubles

缺失

≤0.05% loss on drying

pH值(酸碱度)

3.5-5.0 (25 °C, 29.4 g/L)

mp

398 °C (lit.)

痕量阴离子

chloride (Cl-): ≤0.001%
sulfate (SO42-): ≤0.005%

痕量阳离子

Ca: ≤0.003%
Na: ≤0.001%
Na: ≤0.02%
heavy metals (as Pb): ≤5 ppm

SMILES字符串

[K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O

InChI

1S/2Cr.2K.7O/q;;2*+1;;;;;;2*-1

InChI key

KMUONIBRACKNSN-UHFFFAOYSA-N

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一般描述

重铬酸钾为红橙色固体。它的晶体属于三斜晶系。加热至 600°C 以上时,分解得到氧气、铬酸钾和氧化铬 (III)。在酸性介质中起强氧化剂的作用。它可以通过三氧化二铬与碳酸钾和硝酸盐或氧气的熔融合成。[1]

应用

重铬酸钾可用于制备混合软陶纳米复合材料支撑的重铬酸盐试剂。[2]它也可以作为氧化剂,分别用于伯醇和仲醇选择氧化为相应的醛和酮。[3]

警示用语:

Danger

危险分类

Acute Tox. 2 Inhalation - Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B - Eye Dam. 1 - Muta. 1B - Ox. Sol. 2 - Repr. 1B - Resp. Sens. 1 - Skin Corr. 1B - Skin Sens. 1 - STOT RE 1 Inhalation - STOT SE 3

靶器官

Cardio-vascular system, Respiratory system

储存分类代码

5.1B - Oxidizing hazardous materials

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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