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Merck

79266

Supelco

三甲基苯基氢氧化铵 溶液

~0.5 M (CH3)3N(OH)C6H5 in methanol, for GC derivatization, LiChropur

别名:

苯基三甲基氢氧化铵

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About This Item

线性分子式:
(CH3)3N(OH)C6H5
CAS号:
分子量:
153.22
Beilstein:
3917033
MDL號碼:
分類程式碼代碼:
12000000
PubChem物質ID:
NACRES:
NA.22

等級

for GC derivatization

品質等級

形狀

liquid

品質

LiChropur

反應適用性

reagent type: derivatization reagent
reaction type: Esterifications

濃度

~0.5 M (CH3)3N(OH)C6H5 in methanol

技術

gas chromatography (GC): suitable

雜質

≤0.2% halides (as chloride)

儲存溫度

2-8°C

SMILES 字串

[OH-].C[N+](C)(C)c1ccccc1

InChI

1S/C9H14N.H2O/c1-10(2,3)9-7-5-4-6-8-9;/h4-8H,1-3H3;1H2/q+1;/p-1

InChI 密鑰

HADKRTWCOYPCPH-UHFFFAOYSA-M

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一般說明

Trimethylphenylammonium hydroxide (TMAH) is a methylating reagent.

應用

Learn more in the Product Information
Suitable for the derivatization of amino acids, n-methyl and n-aryl carbamates and fatty acids, clonidine, and substituted phenylureas.
TMAH may be used as a 0.1 mole/litre solution in methanol to determine plasma concentrations of carbamazepine and other anticonvulsant drugs, including phenobarbital, diphenylhydantoin, primidone, and mephenytoin using Gas-Liquid Chromatography.

其他說明

可适用销售限制条款
Reagent for n-methyl and methyl esters.

法律資訊

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

訊號詞

Danger

危險分類

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 1

標靶器官

Eyes

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

51.8 °F - closed cup

閃點(°C)

11 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles


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分析证书(COA)

Lot/Batch Number

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Simultaneous determination of carbamazapine ("Tegretol") and other anticonvulsants in human plasma by gas-liquid chromatography.
J C Roger et al.
Clinical chemistry, 19(6), 590-592 (1973-06-01)
A Ranz et al.
Journal of biochemical and biophysical methods, 69(1-2), 3-14 (2006-03-28)
In the present study, a derivatization method for the determination of acidic herbicides has been investigated. This procedure involves the methylation with the quaternary ammonium salt trimethylanilinium hydroxide (TMAH) directly in the gas chromatographic auto-sampler vial for analysis by gas
Timothy J Jensen et al.
Journal of photochemistry and photobiology. B, Biology, 100(2), 100-111 (2010-06-19)
Five cationic porphyrins bearing one to four -N(CH(3))(3)(+) groups linked to the p-phenyl positions of 5,10,15,20-tetraphenylporphyrin (TPP) were synthesized in order to study the effect of overall charge and its distribution on the cellular uptake, phototoxicity and intracellular localization using
Y El-Nahhal et al.
Journal of agricultural and food chemistry, 48(10), 4791-4801 (2000-10-29)
This study aimed to design formulations of hydrophobic herbicides, alachlor and metolachlor, by adsorbing them on the clay mineral montmorillonite preadsorbed by the small organic cation phenyltrimethylammonium (PTMA). An adsorption model that considers electrostatics and specific binding and the possibility
Alec N Salt et al.
Hearing research, 283(1-2), 14-23 (2011-12-20)
It has been widely believed that drug entry from the middle ear into perilymph occurs primarily via the round window (RW) membrane. Entry into scala vestibuli (SV) was thought to be dominated by local, inter-scala communication between scala tympani (ST)

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