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Merck

426318

Sigma-Aldrich

四甲基氢氧化铵 溶液

ACS reagent

别名:

N,N,N-trimethyl-methanaminium hydroxide, TMAH, TMAOH

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About This Item

线性分子式:
(CH3)4N(OH)
CAS号:
分子量:
91.15
Beilstein:
3558708
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.21

等級

ACS reagent

品質等級

形狀

liquid

濃度

1.0 M±0.02 M in H2O

燃燒殘留物

≤5 ppm

顏色

APHA: ≤10

折射率

n20/D 1.3497

bp

100 °C

密度

1.005 g/mL at 25 °C

負離子痕跡

chloride (Cl-): ≤0.03%

正離子痕跡

K: ≤2 ppm
Na: ≤2 ppm

SMILES 字串

[OH-].C[N+](C)(C)C

InChI

1S/C4H12N.H2O/c1-5(2,3)4;/h1-4H3;1H2/q+1;/p-1

InChI 密鑰

WGTYBPLFGIVFAS-UHFFFAOYSA-M

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應用

四甲基氢氧化铵溶液可用作:
  • 试剂,通过有机催化光诱导桦木还原将芳烃转换为 1,4-环己二烯。
  • 催化剂,通过 2-萘酚、芳香醛和尿素的一锅三组分缩合反应合成1,2-二氢-1-芳基萘-恶嗪-3- 1衍生物。
  • 磁性纳米颗粒的助剂,以提高排斥力的稳定性。
  • 模板,利用热液合成法生成不同大小的分级沸石 T 聚合物。

訊號詞

Danger

危險分類

Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1B - STOT RE 2 Dermal - STOT SE 2

標靶器官

Central nervous system, Liver,thymus

儲存類別代碼

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Eukaryotic cell, 10(9), 1241-1250 (2011-07-05)
Potassium homeostasis is crucial for living cells. In the yeast Saccharomyces cerevisiae, the uptake of potassium is driven by the electrochemical gradient generated by the Pma1 H(+)-ATPase, and this process represents a major consumer of the gradient. We considered that
Qin Chen et al.
Bioresource technology, 117, 186-192 (2012-05-23)
The aim of this study was to explore the synergies of laccase, a ligninolytic enzyme, with cellulose and hemicellulase amendments on ensiled corn stover. Molecular signals of lignin decomposition were observed by tetramethylammonium hydroxide thermochemolysis and gas chromatography-mass spectroscopy (TMAH-GC-MS)
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Langmuir : the ACS journal of surfaces and colloids, 28(4), 2091-2098 (2011-11-08)
A new water-soluble conjugated polymer containing fluorene and boron-dipyrromethene repeat units in the backbones (PBF) that exhibits red emission was synthesized and characterized. Cationic PBF forms uniform nanoparticles with negatively charged disodium salt 3,3'-dithiodipropionic acid (SDPA) in aqueous solution through
Lulu Xie et al.
Science (New York, N.Y.), 342(6156), 373-377 (2013-10-19)
The conservation of sleep across all animal species suggests that sleep serves a vital function. We here report that sleep has a critical function in ensuring metabolic homeostasis. Using real-time assessments of tetramethylammonium diffusion and two-photon imaging in live mice
Man Xu et al.
Environmental science & technology, 47(1), 110-118 (2012-06-12)
Elucidating dissolution kinetics and mechanisms at carbonate mineral-water interfaces is essential to many environmental and geochemical processes, including geologic CO(2) sequestration in deep aquifers. In the present work, effects of background electrolytes on dolomite (CaMg(CO(3))(2)) reactivity were investigated by measuring

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