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Merck
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文件

15450

Sigma-Aldrich

BOC-亮氨酸-OH 水合物

≥99.0% (HPLC)

别名:

BOC- L -亮氨酸

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About This Item

线性分子式:
(CH3)2CHCH2CH(COOH)NHCOOC(CH3)3 xH2O
分子量:
231.29 (anhydrous basis)
EC號碼:
236-073-2
MDL號碼:
MFCD00066067
分類程式碼代碼:
12352209
eCl@ss:
32160406
PubChem物質ID:
329750886
NACRES:
NA.22

品質等級

200

化驗

≥99.0% (HPLC)

形狀

solid

光學活性

[α]20/D −25±0.5°, c = 2% in acetic acid

反應適用性

reaction type: Boc solid-phase peptide synthesis
reaction type: C-H Activation
reagent type: ligand
reaction type: Peptide Synthesis

mp

85-90 °C

應用

peptide synthesis

官能基

amine
carboxylic acid

SMILES 字串

CC(C)C[C@H](NC(OC(C)(C)C)=O)C(O)=O

相关类别

應用

Boc-Leu-OH（Boc-L-亮氨酸）被用于合成强效细胞毒素PM-94128。
Boc保护的亮氨酸（Boc-Leu-OH）可用于产生组合肽文库，并也可用于合成肽模型以研究结构-活性关系。

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

Eyeshields, Gloves, type N95 (US)

Choose from one of the most recent versions:

分析证书(COA)

Lot/Batch Number
BCCM2163
BCCK5745
BCCJ3943
BCCJ0221
BCCH3198

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The synthesis and screening of a combinatorial peptide library for affinity ligands for glycosylated haemoglobin1.
Chen B, et al.
Biosensors And Bioelectronics, 13(7-8), 779-785 (1998)
Multicyclic polypeptide model compounds. 1. Synthesis of a tricyclic amphiphilic. alpha.-helical peptide using an oxime resin, segment-condensation approach.
Osapay G, et al.
Journal of the American Chemical Society, 112(16), 6046-6051 (1990)
Screening of mixture combinatorial libraries for chiral selectors: a reciprocal chromatographic approach using enantiomeric libraries.
Wu Y, et al.
Analytical Chemistry, 71(9), 1688-1691 (1999)
Masaru Enomoto et al.
The Journal of organic chemistry, 74(19), 7566-7569 (2009-09-03)
The enantioselective total synthesis of PM-94128, a potent cytotoxin of microbial origin, was accomplished by a concise nine-step sequence of reactions in 14% overall yield from N-Boc-l-leucine. The synthesis of Y-05460M-A, a one-carbon lower homologue of PM-94128, was also achieved
Hyun-Woong Cho et al.
PloS one, 14(6), e0217745-e0217745 (2019-06-21)
The aim of this study was to investigate the short-term efficacy and safety of Poly-gamma-glutamic acid (γ-PGA) and the immunologic changes in patients with CIN 1. Participants were randomly assigned to one of two groups and orally treated with placebo
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