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Merck

02300

Sigma-Aldrich

D-(+)-苹果酸

unnatural form, ≥97.0% (T)

别名:

(R)-(+)-2-羟基琥珀酸, D-羟基丁二酸

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About This Item

线性分子式:
HO2CCH2CH(OH)CO2H
CAS号:
分子量:
134.09
Beilstein:
1723540
EC號碼:
MDL號碼:
分類程式碼代碼:
51113400
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

≥97.0% (T)

光學活性

[α]20/D +28.0±2°, c = 5.5% in pyridine

品質

unnatural form

mp

98-102 °C (lit.)

SMILES 字串

O[C@H](CC(O)=O)C(O)=O

InChI

1S/C4H6O5/c5-2(4(8)9)1-3(6)7/h2,5H,1H2,(H,6,7)(H,8,9)/t2-/m1/s1

InChI 密鑰

BJEPYKJPYRNKOW-UWTATZPHSA-N

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應用

D-(+)-苹果酸可用于:
  • 作为对映选择性全合成 (−)-erinapyrone B的起始材料。
  • 作为从各种醛、苯胺和亚磷酸二乙酯合成α-氨基膦酸酯的手性有机催化剂。

象形圖

CorrosionExclamation mark

訊號詞

Danger

危險聲明

危險分類

Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


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分析证书(COA)

Lot/Batch Number

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Concise Total Synthesis of (-)-Erinapyrone B from D-(+)-Malic Acid
Samala R, et al.
Synthetic Communications, 44(4), 500-506 (2014)
K Leckel et al.
Clinical and experimental immunology, 134(2), 238-245 (2003-11-18)
Immunosuppression correlates with the development and recurrence of cancer. Mycophenolate mofetil (MMF) has been shown to reduce adhesion molecule expression and leucocyte recruitment into the donor organ. We have hypothesized that MMF might also prevent receptor-dependent tumour dissemination. Therefore, we
R Kaminsky et al.
Tropical medicine & international health : TM & IH, 1(2), 255-263 (1996-04-01)
The unique features of purine salvage systems of pathogenic haemoflagellates render them selectively susceptible to the cytotoxic effects of purine analogues. A series of acyclic nucleoside phosphonates were evaluated for activity against pathogenic haemoflagellates in vitro. One of the phosphonylmethoxyalkylpurines
C Orskov et al.
FEBS letters, 247(2), 193-196 (1989-04-24)
We developed specific, C-terminal radioimmunoassays for three proglucagon (PG) fragments: PG 151-158, PG 151-160 and PG 126-159 (glucagon-like peptide-2 (GLP-2] in order to determine the exact C-terminal sequence of the newly isolated GLP-2 in man and pig. The antigens and
One pot green synthesis of α-aminophosphonates with D-Malic acid as an organocatalyst
AIP Conference Proceedings, 1860(1), 020057-020057 (2017)

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