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H11602

Sigma-Aldrich

六甲基磷酰三胺

99%

别名:

HMPA, 三(二甲氨基)氧膦, 六甲基磷酸三胺

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About This Item

线性分子式:
[(CH3)2N]3PO
CAS号:
680-31-9
分子量:
179.20
Beilstein:
1099903
EC號碼:
211-653-8
MDL號碼:
MFCD00008303
分類程式碼代碼:
12352111
PubChem物質ID:
24895433
NACRES:
NA.22
价格与库存信息目前不能提供

蒸汽密度

6.18 (vs air)

品質等級

200

蒸汽壓力

0.07 mmHg ( 25 °C)

化驗

99%

折射率

n20/D 1.459 (lit.)

bp

230-232 °C/740 mmHg (lit.)

mp

7 °C (lit.)

密度

1.03 g/mL at 25 °C (lit.)

SMILES 字串

CN(C)P(=O)(N(C)C)N(C)C

InChI

1S/C6H18N3OP/c1-7(2)11(10,8(3)4)9(5)6/h1-6H3

InChI 密鑰

GNOIPBMMFNIUFM-UHFFFAOYSA-N

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一般說明

六甲基磷酰胺是一种极性非质子溶剂。[1]

應用

六甲基磷酰胺可用作以下过程的溶剂：
  • 通过与烷基卤化物反应将羧酸盐转化为酯。[2]
  • 通过硫醇离子亲核置换未活化的芳基卤化物来合成芳基硫醚。[3]
  • 通过高温溶液缩聚将二醛和二胺合成聚甲亚胺（PAZs）。[4]

象形圖

Health hazardCorrosion
GHS08,GHS05

訊號詞

Danger

危險聲明

H314,H340,H350

危險分類

Carc. 1B - Eye Dam. 1 - Muta. 1B - Skin Corr. 1C

儲存類別代碼

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類（WGK）

WGK 3

閃點（°F）

291.2 °F - closed cup

閃點（°C）

144 °C - closed cup

個人防護裝備

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
WXBF2939V
WXBF3238V
WXBF3674V
WXBF2401V
WXBD7028V

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Hexamethylphosphoramide
Normant H.
Angewandte Chemie (International Edition in English), 6(12), 1046-1067 (1967)
Nucleophilic aromatic substitution reactions of unactivated aryl halides with thiolate ions in hexamethylphosphoramide.
Cogolli P, et al.
The Journal of Organic Chemistry, 44(15), 2642-2646 (1979)
Controlled/?Living? Reverse Atom Transfer Radical Polymerization of a Monocyclic Olefin, Methyl 1-Cyclobutenecarboxylate.
Chen X P, et al.
Macromolecules, 35(11), 4277-4281 (2002)
Optical and structural study of thin film of polyazomethine with triphenylamine unit prepared via spin-coating method.
Palewicz M, et al.
Polymer Bull., 66(1), 65-76 (2011)
Ge Gao et al.
Proceedings of the National Academy of Sciences of the United States of America, 101(15), 5417-5420 (2004-03-18)
It is found that the addition of hexamethylphosphoramide to the solution of an alkyne, Et(2)Zn, and (S)-1,1'-bi-2-naphthol in methylene chloride allows the generation of an alkynylzinc at room temperature and shows highly enantioselective additions to aldehydes. The mild condition for
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    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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