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Key Documents

936006

Sigma-Aldrich

Sodium bis(trifluoromethanesulfonyl)imide solution

new
greener alternative

in ethylene carbonate, dimethyl carbonate, 1.0 M NaTFSI in EC/DMC=50/50 (v/v), battery grade

别名:

1.0 M NaTFSI in EC/DMC electrolyte

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About This Item

分類程式碼代碼:
12352600

等級

battery grade

品質等級

形狀

solution

環保替代產品特色

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

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濃度

0.95-1.05 M (NaPF6)

雜質

≤100 ppm H2O

負離子痕跡

chloride (Cl-): ≤200 ppm
sulfate (SO42-): ≤200 ppm

應用

battery manufacturing

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一般說明

Sodium bis(trifluoromethanesulfonyl)imide solution in ethylene carbonate and dimethylcarbonate, 1.0 M NaTFSI in EC/DMC=50/50 (v/v) is a clear solution of battery grade sodium bis(trifluoromethanesulfonyl)imide (NaTfSI) dissolved in binary mixture of EC/DMC=50/50 (v/v).
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應用

The main application of 1.0 M NaTFSI in EC/DMC=50/50 (v/v), battery grade is as an electrolyte for sodium-ion batteries. NaTFSI-based electrolytes have advantages over NaPF6-based electrolytes because they are less sensitive to hydrolysis, safer to handle, and are more stable thermally and electrochemically. NaTFSI offers improved higher thermal stability compared to NaPF6 and NaBF4, and higher conductivity than NaTfO. The blend of ethylene carbonate and dimethyl carbonate achieves a low viscosity and good wettability of most polyolefin separators.[1,2]

訊號詞

Danger

危險分類

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - STOT RE 2 Oral

標靶器官

Kidney

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

77.0 °F

閃點(°C)

25 °C


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Non-aqueous electrolytes for sodium-ion batteries
A. Ponrouch, et al.
Journal of Material Chemistry A, 3, 22-42 (2015)
SEI Composition on Hard Carbon in Na-Ion Batteries After Long Cycling: Influence of Salts (NaPF6, NaTFSI) and Additives (FEC, DMCF)
J. Fondard ,et al.
Journal of the Electrochemical Society, 167 (2020)

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