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Merck

933953

Sigma-Aldrich

Sodium difluoro(oxalato)borate

greener alternative

≥99%, battery grade

别名:

NaDFOB, NaFOB, Sodium difluoro(ethanedioato)borate

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About This Item

经验公式(希尔记法):
C2BF2NaO4
分子量:
159.82
分類程式碼代碼:
12352104
NACRES:
NA.21

等級

battery grade

品質等級

描述

Application: Battery manufacturing

化驗

≥99%

形狀

powder

環保替代產品特色

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

雜質

≤0.2% H2O

負離子痕跡

chloride (Cl-): ≤50 ppm
sulfate (SO42-): ≤20 ppm

正離子痕跡

Ca: ≤20 ppm
K: ≤20 ppm
Mg: ≤20 ppm

應用

battery manufacturing

環保替代類別

SMILES 字串

O=C1C(O[B-](F)(F)([Na+])O1)=O

一般說明

Sodium difluoro(oxalato)borate, also referred to as NaDFOB, is a high-purity and low-water content white crystalline powder that has become increasingly popular in the field of battery technology. NaDFOB is the sodium equivalent of lithium difluoro(oxalato)borate and is soluble in polar organic solvents (>1.0 M in carbonates), making it ideal for use in battery electrolytes. It exhibits excellent electrochemical stability, surpassing NaClO4, with NaDFOB-based carbonate electrolytes showing electrochemical stability windows above 5.5V vs Na+/Na. Our NaDFOB is manufactured to the highest standards to ensure its purity, enabling it to be used effectively in a wide range of battery applications.
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應用

Sodium-difluoro(oxalato)borate, anhydrous and battery-grade with a purity of ≥99%, is a versatile electrolyte additive for sodium-ion batteries (SIBs). NaDFOB demonstrates superior compatibility with a range of solvents commonly employed in SIBs, unlike NaClO4 and NaPF6, which exhibit solvent-dependent performances. Additionally, NaDFOB is stable and does not produce any toxic or hazardous substances upon contact with air and water. A recent study found that the incorporation of NaDFOB as an additive significantly enhances the charge-discharge capacity and cycling performance of graphite anodes. Another study suggests that NaDFOB contributes to the formation of a stable solid electrolyte interphase (SEI) film on the surface of graphite anodes, resulting in a highly stable electrolyte/electrode interface. With these benefits, Sodium-difluoro(oxalato)borate is a promising solution for improving the performance and stability of sodium-ion batteries in various applications.

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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Sodium Difluoro(oxalato)borate as An Electrolyte Additive to Improve the Electrochemical Performance of Graphite Anode
Yang-yang Yao, et al.
International Journal of Electrochemistry, 21, 387-392 (2015)
Application of Partially Fluorinated Ether for Improving Performance of Lithium/Sulfur Batteries
Lu Hai, et al.
Journal of the Electrochemical Society, 162 (2015)
Juner Chen et al.
Chemical communications (Cambridge, England), 51(48), 9809-9812 (2015-05-20)
A new electrolyte salt, sodium-difluoro(oxalato)borate (NaDFOB), was synthesized and studied, which enables excellent reversible capacity and high rate capability when used in Na/Na0.44MnO2 half cells. NaDFOB has excellent compatibility with various common solvents used in Na-ion batteries, in strong contrast

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