903973

Thianthrene S-oxide

≥95%

• 别名: Non-fluorinated sulfoxide-based thianthrene reagent, Thianthrene 5-oxide
• 经验公式（希尔记法）: C₁₂H₈OS₂
• CAS号: 2362-50-7
• 分子量: 232.32
• MDL號碼: MFCD01464038
• 分類程式碼代碼: 12352119
• NACRES: NA.22

属性

• 化驗: ≥95%
• 形狀: powder
• 官能基: sulfoxide; thioether
• 儲存溫度: 2-8°C
• InChI: 1S/C12H8OS2/c13-15-11-7-3-1-5-9(11)14-10-6-2-4-8-12(10)15/h1-8H
• InChI 密鑰: NYVGTLXTOJKHJN-UHFFFAOYSA-N

说明

應用

Thianthrene S-oxide is a sulfoxide-based thianthrene reagent for late-stage C-H functionalization. Developed by the Ritter Lab, C-H functionalization by thianthrenation proceeds with >99% selectivity and furnishes functionalized arenes serving as synthetic linchpins for further participation in diverse transformations. Nonfluorinated thianthrene S-oxide is best used for all arenes more electron-rich than anisole. For other arenes, the fluorinated TFT S-oxide (903981) was demonstrated as the thanthrenation reagent.

其他說明

Site-selective and versatile aromatic C-H functionalization by thianthrenation

Video: Site-selective C-H functionalization by thianthrenation

In the Pipeline: New Chemistry, Making New Things

Ti(Phen)(OC₂H₅)₂Cl₂: a highly efficient pre-?catalyst for selective oxidation of organic sulfides to sulfoxides by hydrogen peroxide

法律資訊

Patent Application EP18204755.5
This product is manufactured pursuant to a license with Studiengesellschaft Kohle mbH

安全信息

• 儲存類別代碼: 11 - Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable