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方案
≥97.0%
表单
liquid
反应适用性
core: titanium
reagent type: Lewis acid
reagent type: catalyst
折射率
n20/D 1.464 (lit.)
沸点
232 °C (lit.)
mp
14-17 °C (lit.)
密度
0.96 g/mL at 20 °C (lit.)
SMILES字符串
CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C
InChI
1S/4C3H7O.Ti/c4*1-3(2)4;/h4*3H,1-2H3;/q4*-1;+4
InChI key
VXUYXOFXAQZZMF-UHFFFAOYSA-N
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一般描述
钛(IV)异丙醇是一种路易斯酸催化剂,用于夏普莱斯不对称环氧化反应等有机反应。
应用
通过两步溶胶-凝胶法从钛酸异丙酯形成的新型金属氧化物/膦酸盐杂化物。 钛酸锶钡薄膜起始物质。用于合成介孔钛硅材料,后者是一种可能用于放射废物清洁的离子交换材料。 参与合成TiO2纳米晶体紫精电子受体复合体构成的异超分子,后者的光诱导电子转移特性已经过研究。
注意
储存中可能变色
其他说明
用于无形非对称烯丙醇环氧化反应的添加剂;用于中性条件下多种醇酯交换反应的催化剂
警示用语:
Warning
危险声明
危险分类
Eye Irrit. 2 - Flam. Liq. 3 - STOT SE 3
靶器官
Central nervous system
储存分类代码
3 - Flammable liquids
WGK
WGK 1
闪点(°F)
105.8 °F - Pensky-Martens closed cup
闪点(°C)
41 °C - Pensky-Martens closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
其他客户在看
R. Imwinkelried et al.
Organic Syntheses, 65, 230-230 (1987)
Catalyst design for alkene epoxidation by molecular analogues of heterogeneous titanium-silicalite catalysts
Sole DA, et al.
ACS Catalysis, 10, 4737-4750 (2020)
Henrique Antonio Mendonça Faria et al.
Materials science & engineering. C, Materials for biological applications, 56, 260-268 (2015-08-08)
The structural and electronic properties of titanium oxide nanotubes (TiO2) have attracted considerable attention for the development of therapeutic devices and imaging probes for nanomedicine. However, the fluorescence response of TiO2 has typically been within ultraviolet spectrum. In this study
Yann Sarazin et al.
Dalton transactions (Cambridge, England : 2003), (2)(2), 340-350 (2005-12-21)
The reactions of the bulky amino-bis(phenol) ligand Me(2)NCH(2)CH(2)N[CH(2)-3,5-Bu(t)(2)-C(6)H(2)OH-2](2)(1-H(2)) with Zn[N(SiMe(3))(2)](2)(4), [Mg[N(SiMe(3))(2)](2)](2)(5) and Ca[N(SiMe(3))(2)](2)(THF)(2)(6) yield the complexes 1-Zn, 1-Mg and 1-Ca in good yields. The X-ray structure of 1-Ca showed the complex to be dimeric, with calcium in a distorted octahedral
Alexander V Agafonov et al.
Polymers, 12(9) (2020-09-24)
Electrorheological elastomers based on polydimethylsiloxane filled with hydrated titanium dioxide with a particle size of 100-200 nm were obtained by polymerization of the elastomeric matrix, either in the presence, or in the absence, of an external electric field. The viscoelastic
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