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Merck

751855

Sigma-Aldrich

肼 溶液

1 M in acetonitrile

别名:

Hydrazine, Nitrogen hydride

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About This Item

线性分子式:
NH2NH2
CAS号:
分子量:
32.05
Beilstein:
878137
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

形狀

liquid

濃度

1 M in acetonitrile

折射率

n20/D 1.348

密度

0.779 g/mL at 25 °C

SMILES 字串

NN

InChI

1S/H4N2/c1-2/h1-2H2

InChI 密鑰

OAKJQQAXSVQMHS-UHFFFAOYSA-N

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一般說明

肼(N2H4)溶液是有机合成应用中常见的还原剂和多用途试剂。它可以将多种官能团,如酮、醛、亚胺、硝基化合物、叠氮化物和硝酸&盐,还原来其相应的胺。它还在杂环化合物,如吡唑和吡唑咻等合成中充当氮的来源。

應用

(乙腈中的)肼溶液可用作还原源,用于使用金属有机框架(MOF)作为非均相催化剂,还原烯烃、炔烃和α,β-不饱和酯中的碳-碳多键。它也可用作由2-氨基嘧啶和α-溴羰基化合物合成多取代2-氨基咪唑。

相關產品

产品编号
说明
价格

訊號詞

Danger

危險分類

Acute Tox. 3 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 2 - Carc. 1B - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - Skin Sens. 1

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

41.0 °F

閃點(°C)

5 °C


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D P Elder et al.
Journal of pharmaceutical and biomedical analysis, 54(5), 900-910 (2010-12-15)
This is the latest of a series of reviews focused on the analysis of genotoxic impurities. This review summarises the analytical approaches reported in the literature relating to hydrazine, hydrazines, hydrazides and hydrazones. It is intended to provide guidance for
M Vogel et al.
Fresenius' journal of analytical chemistry, 366(8), 781-791 (2001-03-03)
Hydrazine reagents are a well-known group of derivatizing agents for the determination of aldehydes and ketones in liquid and gaseous samples. Within this article, the most important hydrazine reagents are critically summarized, and their major applications in different fields, including
Nilay Hazari
Chemical Society reviews, 39(11), 4044-4056 (2010-06-24)
One of the most challenging problems in small molecule activation is the development of a homogeneous catalyst for converting dinitrogen into ammonia at ambient temperatures and atmospheric pressure. A catalytic cycle based on molybdenum that converts dinitrogen into ammonia has
Min Yuan et al.
Dalton transactions (Cambridge, England : 2003), (31)(31), 6078-6088 (2010-05-08)
A combination of unique solvent properties of hydrazine enables the direct dissolution of a range of metal chalcogenides at ambient temperature, rendering this an extraordinarily simple and soft synthetic approach to prepare new metal chalcogenide-based materials. The extended metal chalcogenide
Tino Wilson Sanchez et al.
Bioorganic & medicinal chemistry, 21(4), 957-963 (2013-01-12)
Human lens epithelium-derived growth factor (LEDGF)/p75 plays an important role in the HIV life cycle by stimulating integrase (IN)-led viral DNA integration into cellular chromosomes. Mechanistic studies show the majority of IN inhibitors chelate magnesium ions in the catalytic active

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