746339

二氯三苯基膦[双（2-（乙硫基）乙基）胺]钌（II）

97%

• 别名: Ru-SNS catalyst
• 经验公式（希尔记法）: C₂₆H₃₄Cl₂NPRuS₂
• CAS号: 1462397-86-9
• 分子量: 627.63
• MDL编号: MFCD26960799
• UNSPSC代码: 12161600
• PubChem化学物质编号: 329765759
• NACRES: NA.22

属性

• 质量水平: 100
• 方案: 97%
• 表单: solid
• 反应适用性: core: ruthenium; reagent type: catalyst
• 环保替代产品特性: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• mp: 300-310 °C
• 环保替代产品分类: Aligned,
• SMILES字符串: CCSCCN([H])CCSCC.Cl[Ru]Cl.P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3
• InChI: 1S/C18H15P.C8H19NS2.2ClH.Ru/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-3-10-7-5-9-6-8-11-4-2;;;/h1-15H;9H,3-8H2,1-2H3;2*1H;/q;;;;+2/p-2
• InChI key: ZQGMNGJIEYHKBR-UHFFFAOYSA-L

说明

一般描述

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

应用

Catalyst for hydrogenation of esters to alcohols. Greener alternative to stoichiometric hydride reagents.

Replacing Phosphorus with Sulfur for the Efficient Hydrogenation of Esters

Catalyst for the hydrogenation of esters to alcohols.

其他说明

"The mer-SNS complexes form isomers in solution. This is due to the different arrangements of the SEt groups relative to the SNS ligand plane. Two of the isomers have eclipsed SEt groups (arranged on one side of the SNS plane), and the third isomer has staggered SEt groups (occupying the opposite sides of the SNS plane)."

法律信息

This Product is licensed from GreenCentre Canada for non-commercial, research use only. Please contact GreenCentre Canada for information regarding commercial use of Product.

安全信息

• 象形图: GHS06
• 警示用语：: Danger
• 危险声明: H302 + H312,H331
• 预防措施声明: P280 - P301 + P312 + P330 - P302 + P352 + P312 - P304 + P340 + P311
• 危险分类: Acute Tox. 3 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral
• 储存分类代码: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• WGK: WGK 3
• 闪点(°F): Not applicable
• 闪点(°C): Not applicable