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695459

Sigma-Aldrich

1,3,5,7-四甲基-6-苯基-2,4,8-三氧-6-磷金刚烷

97%

别名:

1,3,5,7-四甲基-8-苯基-2,4,6-三氧-8-磷酸三环 [3.3.1.1 3,7 ] 癸烷, meCgPPh

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About This Item

经验公式（希尔记法）:
C16H21O3P
CAS号:
97739-46-3
分子量:
292.31
MDL號碼:
MFCD30541356
分類程式碼代碼:
12352005
PubChem物質ID:
329761744
NACRES:
NA.22
价格与库存信息目前不能提供

品質等級

100

化驗

97%

形狀

solid

反應適用性

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
reaction type: Cross Couplings

mp

106-111 °C

官能基

phosphine

SMILES 字串

CC12CC3(C)OC(C)(CC(C)(O1)P3c4ccccc4)O2

InChI

1S/C16H21O3P/c1-13-10-15(3)19-14(2,17-13)11-16(4,18-13)20(15)12-8-6-5-7-9-12/h5-9H,10-11H2,1-4H3

InChI 密鑰

AVVSJWUWBATQBX-UHFFFAOYSA-N

相关类别

應用

使用1,3,5,7-四甲基-6-苯基-2,4,8-三恶-6-磷酰金刚烷：
  • 作为配体合成配合物用于氢甲酰化反应催化。[1][2]
  • 用于通过分子内环化羰基化反应催化二苯并b,f][1,4]]氧氮杂卓-11(10H)-酮[3]和3-甲基-3,4-二氢香豆素的合成。[4]

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
SHBJ8427
SHBJ3444
SHBH5553V
SHBG7553V
SHBF9423V

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Phenylphosphatrioxa-adamantanes: bulky, robust, electron-poor ligands that give very efficient rhodium (I) hydroformylation catalysts
Baber RA, et al.
Dalton Transactions, 6, 1079-1085 (2005)
Synthesis of Dibenzo [b, f][1, 4] oxazepin-11 (10 H)-ones via Intramolecular Cyclocarbonylation Reactions Using PdI2/Cytop 292 as the Catalytic System
Yang Q, et al.
The Journal of Organic Chemistry, 75(18), 6297-6299 (2010)
PdI2-Catalyzed Regioselective Cyclocarbonylation of 2-Allyl Phenols to Dihydrocoumarins
Ame?zquita-Valencia M and Alper H
Organic Letters, 16(22), 5827-5829 (2014)
Diastereoselective and Branched-Aldehyde-Selective Tandem Hydroformylation-Hemiaminal Formation: Synthesis of Functionalized Piperidines and Amino Alcohols
Pittaway R, et al.
Organic Letters, 19(11), 2845-2848 (2017)

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Amines and phosphines in nucleophilic catalysis are discussed, addressing the air sensitivity of phosphines.

Trialkylphosphine for MBH Reactions

Amines and phosphines in nucleophilic catalysis are discussed, addressing the air sensitivity of phosphines.

Trialkylphosphine for MBH Reactions

Amines and phosphines in nucleophilic catalysis are discussed, addressing the air sensitivity of phosphines.

Trialkylphosphine for MBH Reactions

Amines and phosphines in nucleophilic catalysis are discussed, addressing the air sensitivity of phosphines.

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