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683175

Sigma-Aldrich

Chiralyst P374

Umicore

别名:

双（降冰片二烯）铑 (I) 四氟硼酸盐, [Rh(nbd)Cl]4, 双（双环[2.2.1]庚-2,5-二烯）四氟硼酸铑, 双（降冰片二烯）（四氟硼酸）铑, Rh(nbd)2BF4

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About This Item

线性分子式:
[Rh(NBD)BF4
CAS号:
36620-11-8
分子量:
373.99
MDL號碼:
MFCD00671775
分類程式碼代碼:
12161600
PubChem物質ID:
329760802
NACRES:
NA.22

品質等級

100

形狀

solid

反應適用性

core: rhodium
reagent type: catalyst

mp

136.9-139.9 °C

SMILES 字串

[Rh+].F[B-](F)(F)F.C1C2C=CC1C=C2.C3C4C=CC3C=C4

InChI

1S/2C7H8.BF4.Rh/c2*1-2-7-4-3-6(1)5-7;2-1(3,4)5;/h2*1-4,6-7H,5H2;;/q;;-1;+1/t2*6-,7+;;

InChI 密鑰

HAYDJWBQWOEERB-JAGGYEKFSA-N

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相关类别

應用

用于不对称和交叉偶联催化的 Umicore 预催化剂
双（降冰片二烯）铑(I) 四氟硼酸可用作催化剂来合成以下物质：
  • 通过芳基硼酸的1,4加成形成丁烯羟酸内酯
  • 手性β芳基取代的酮和酯。
  • β-由 β-芳氧基α,γ-不饱和酯形成芳氧基碳酸酯。

法律資訊

Umicore 产品

更多信息请参见 www.pmc.umicore.com

象形圖

Corrosion
GHS05

訊號詞

Danger

危險聲明

H314

危險分類

Eye Dam. 1 - Skin Corr. 1B

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Enantioselective Synthesis of ?-Aryloxycarboxylic Esters via Asymmetric Hydrogenation of ?-Aryloxy-?, ?-Unsaturated Esters
Stewart GW, et al.
Organic Letters, 14(21), 5440-5443 (2012)
Practical method for asymmetric addition of arylboronic acids to ?, ?-unsaturated carbonyl compounds utilizing an in situ prepared rhodium catalyst
Lukin K, et al.
The Journal of Organic Chemistry, 74(2), 929-931 (2008)
Determination of the absolute configuration of two ?v?6 integrin inhibitors for the treatment of idiopathic pulmonary fibrosis and investigations on the asymmetric 1, 4-addition of arylboronic acids to crotonate esters bearing a C4-oxygen substituent
Procopiou PA, et al.
Tetrahedron Asymmetry, 28(10), 1384-1393 (2017)

商品

Umicore Precatalysts

Precatalysts for asymmetric catalysis offer batch-to-batch consistency in a range of catalytic reactions, supporting diverse research needs.

Umicore Precatalysts

Precatalysts for asymmetric catalysis offer batch-to-batch consistency in a range of catalytic reactions, supporting diverse research needs.

Umicore Precatalysts

Precatalysts for asymmetric catalysis offer batch-to-batch consistency in a range of catalytic reactions, supporting diverse research needs.

Umicore Precatalysts

Precatalysts for asymmetric catalysis offer batch-to-batch consistency in a range of catalytic reactions, supporting diverse research needs.

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