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Merck

445746

Sigma-Aldrich

聚甲基丙烯酸甲酯

average Mw ~350,000 by GPC

别名:

PMMA, 聚(甲基丙烯酸甲酯)

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About This Item

线性分子式:
[CH2C(CH3)(CO2CH3)]n
CAS号:
MDL编号:
UNSPSC代码:
12162002
PubChem化学物质编号:
NACRES:
NA.23
价格与库存信息目前不能提供

表单

powder

自燃温度

580 °F

分子量

average Mw ~350,000 by GPC

比浓粘度

150-160 cm3/g(20 °C)(lit.)

酸值

<1 mg KOH/g

转变温度

Tg (DSC) 105 °C (midpoint)

溶解性

alcohols and aliphatic hydrocarbons: insoluble
esters, ketones, aromatics and glycol ethers: soluble

密度

1.17 g/mL at 25 °C

InChI

1S/C5H9O2/c1-4(2)5(6)7-3/h1-3H3

InChI key

PMAMJWJDBDSDHV-UHFFFAOYSA-N

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一般描述

在惰性气氛中研究了 PMMA(平均分子量 ~350,000g mol-1)的热降解行为,观察到四个失重步骤。[1]

应用

PMMA(平均分子量 ~350,000 g mol-1) 含有 Fe2O3 和 TiO2 填料可用作阻燃剂。[2]
用于涂料的颜料润湿粘合剂。

特点和优势

提供硬度、耐候性、耐光性和耐化学性。

储存分类代码

11 - Combustible Solids

WGK

nwg

个人防护装备

Eyeshields, Gloves, type N95 (US)


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Thermal degradation of poly (methyl methacrylate)(PMMA): modelling of DTG and TG curves.
Ferriol M., et al.
Polymer Degradation and Stability, 79(2), 271-281 (2003)
Influence of TiO2 and Fe2O3 fillers on the thermal properties of poly (methyl methacrylate)(PMMA).
Laachachi A.,et al.
Material Matters, 59(1), 36-39 (2005)
Distortions of iris and anterior lens capsule OCT images by ICRS.
Hosik Hwang et al.
Journal of refractive surgery (Thorofare, N.J. : 1995), 29(3), 155-156 (2013-03-01)
Bo Chen et al.
Journal of controlled release : official journal of the Controlled Release Society, 140(3), 203-209 (2009-05-26)
Water-soluble polymers for the delivery of chemotherapeutic drugs passively target solid tumors as a consequence of reduced renal clearance and the enhanced permeation and retention (EPR) effect. Elimination of the polymers in the kidney occurs due to filtration through biological
François Therriault-Proulx et al.
Physics in medicine and biology, 58(7), 2073-2084 (2013-03-09)
The goal of this study was to evaluate the nature of the stem effect light produced within an optical fiber, to quantify its composition, and to evaluate the efficiency of the chromatic technique to remove the stem effect. Spectrometry studies

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Professor Aran discusses engineering graphene-based materials through careful functionalization, enabling diverse applications.

Professor Aran discusses engineering graphene-based materials through careful functionalization, enabling diverse applications.

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Questions

1–3 of 3 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  3. Welcher Initiator wurde für die Polymerisation verwendet?

    1 answer
    1. Details around the synthesis and/or preparation are considered proprietary.

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