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Merck

378151

Sigma-Aldrich

2,2'-氧化二乙酰氯

95%

别名:

2,2′-Oxydiacetyl chloride

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About This Item

线性分子式:
O(CH2COCl)2
CAS号:
分子量:
170.98
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

化驗

95%

形狀

liquid

折射率

n20/D 1.473 (lit.)

bp

84-87 °C/2 mmHg (lit.)

密度

1.439 g/mL at 25 °C (lit.)

官能基

acyl chloride
ether

SMILES 字串

ClC(=O)COCC(Cl)=O

InChI

1S/C4H4Cl2O3/c5-3(7)1-9-2-4(6)8/h1-2H2

InChI 密鑰

GTZXSBQCNBNWPK-UHFFFAOYSA-N

一般說明

Diglycolyl chloride (2,2′-Oxydiacetyl chloride) is an acid halide.

應用

Diglycolyl chloride is suitable for use in the synthesis of ply(ether ester). It may be used in the synthesis of:
  • chiral diphenyl substituted polyether-diester compounds
  • morpholine dione analog (IMDNQ)
  • salicylic acid (SA)- based diacids
Diglycolyl chloride may be used in the synthesis of the following compounds:
  • diazadibenzo-18-crown-6 diamide
  • diazadi(tert-butylbenzo)-18-crown-6 diamide
  • surfen derivative

象形圖

Corrosion

訊號詞

Danger

危險聲明

危險分類

Eye Dam. 1 - Skin Corr. 1B

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

235.4 °F - closed cup

閃點(°C)

113 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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分析证书(COA)

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Ashley L Carbone et al.
Macromolecular rapid communications, 30(12), 1021-1021 (2010-02-18)
Fast-degrading, salicylate-based poly(anhydride-esters) were designed to degrade and release the active component, salicylic acid (SA), within 1 week. The polymer degradation was enhanced by using shorter or oxygen-containing aliphatic chains. A copolymer of diglycolic acid was also made with a
Synthesis and CO2 Solubility Studies of Poly (ether carbonate) s and Poly (ether ester) s Produced by Step Growth Polymerization.
Tan B, et al.
Macromolecules, 38(5), 1691-1698 (2005)
J C Aguilar et al.
Talanta, 54(6), 1195-1204 (2008-10-31)
The ligands 4,7-diaza-2,3,8,9-dibenzo-15-crown-5 (L1), 4,10-diaza-2,3,11,12-dibenzo-18-crown-6 (L2), 4,10-diaza-2,3,11,12-di(4'-tert-butylbenzo)-18-crown-6 (L3) and N,N-di(methylenecarboxyethoxy) 4,10-diaza-2,3,11,12-dibenzo-18-crown-6 (L4) have been prepared. Partition coefficients and acid dissociation constants for these four diazadibenzocrown ether compounds were determined in water-chloroform. Their effectiveness was assessed in solvent extraction of Pb(2+)
Small molecule antagonists of cell-surface heparan sulfate and heparin-protein interactions.
Weiss RJ, et al.
Chemical Science, 6(10), 5984-5993 (2015)
Preparation of chiral diphenyl substituted polyether-diester compounds.
Bradshaw JS, et al.
The Journal of Organic Chemistry, 47(7), 1229-1232 (1982)

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