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346462

Sigma-Aldrich

硝酸氧锆 水合物

technical grade

别名:

硝酸锆酰 水合物

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About This Item

线性分子式:
ZrO(NO3)2 · xH2O
CAS号:
14985-18-3
分子量:
231.23 (anhydrous basis)
EC 号:
237-529-3
MDL编号:
MFCD00149896
UNSPSC代码:
12352302
PubChem化学物质编号:
24861411
NACRES:
NA.23
价格与库存信息目前不能提供

等级

technical grade

表单

powder

组成

Degree of hydration, ~6

浓度

25-30% Zr (after ignition to oxide, gravimetric)

应用

battery manufacturing

SMILES字符串

O=[Zr++].[H]O[H].[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/2NO3.H2O.O.Zr/c2*2-1(3)4;;;/h;;1H2;;/q2*-1;;;+2

InChI key

BGMQNYCWALSARE-UHFFFAOYSA-N

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相关类别

一般描述

Zirconium(IV) oxynitrate hydrate is an inorganic salt primarily used as a precursor for the synthesis of zirconium nanoparticles, to fabricate Li-ion batteries, and as a catalyst in various chemical reactions.[1] [2]

应用

Zirconium(IV) oxynitrate hydrate can be used:
  • As a starting material to prepare electrolytes for Li-ion batteries.[1]
  • For the surface modification of cathodes, to enhance the electrochemical properties of all-solid-state batteries.[3]
  • As a precursor for surfactant-free synthesis of zirconia nanostructures.[4]
It can also be used as a catalyst for:
  • Regiospecific alcoholysis and aminolysis of epoxides.[2]
  • One-pot synthesis and oxidation of bis- and tris(indolyl)methanes into conjugated chromophores.[5]

警示用语：

Danger

危险声明

H272,H302,H314

危险分类

Acute Tox. 4 Oral - Eye Dam. 1 - Ox. Sol. 2 - Skin Corr. 1B

补充剂危害

EUH071

储存分类代码

5.1B - Oxidizing hazardous materials

WGK

WGK 1

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCX1467
MKCX1469
MKCT6081
MKCV0459
MKCV0458

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The Structure and Electrical Properties of Li7La3Zr1.0Sn1.0O12 as Electrolyte Material for Li-ion Batteries
Siti Nur Adlina Norazman, et al.
Advances in Science and Technology, 118, 27-32 (2022)
Zirconia Nanostructures: Novel Facile Surfactant-Free Preparation and Characterization
Sahar Zinatloo-Ajabshir, et al.
International Journal of Applied Ceramic Technology, 13, 108-115 (2016)
Mild regiospecific alcoholysis and aminolysis of epoxides catalyzed by zirconium(IV) oxynitrate
Sandip S. Shinde, et al.
Tetrahedron Letters, 56, 5916-5919 (2015)
Zirconium(IV)-catalyzed one-pot synthesis and oxidation of bis- and tris(indolyl)methanes into conjugated chromophores as new pH indicators or calorimetric chemosensors for transition metals
Alireza Khorshidi, et al.
Tetrahedron Letters, 55, 3873-3877 (2014)
Enhanced electrochemical properties of all-solid-state batteries using a surface-modified LiNi 0.6 Co 0.2 Mn 0.2 O 2 Cathode
Chung Bum Lim, et al.
Journal of Electrochemical Science and Technology, 11, 411-420 (2020)

Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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