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330744

Sigma-Aldrich

四丙基高钌酸铵

97%

别名:

TPAP

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About This Item

线性分子式:
(CH3CH2CH2)4NRuO4
CAS号:
114615-82-6
分子量:
351.43
MDL號碼:
MFCD00074914
分類程式碼代碼:
12352116
PubChem物質ID:
24859883
NACRES:
NA.22
价格与库存信息目前不能提供

品質等級

200

化驗

97%

形狀

solid

反應適用性

reagent type: oxidant

mp

~160 °C (dec.) (lit.)

官能基

amine

SMILES 字串

[O-][Ru](=O)(=O)=O.CCC[N+](CCC)(CCC)CCC

InChI

1S/C12H28N.4O.Ru/c1-5-9-13(10-6-2,11-7-3)12-8-4;;;;;/h5-12H2,1-4H3;;;;;/q+1;;;;-1;

InChI 密鑰

NQSIKKSFBQCBSI-UHFFFAOYSA-N

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相关类别

一般說明

过钌酸四丙基铵是一种温和的氧化剂，可用于将醇氧化为相应的羰基化合物。它是一种不挥发、空气稳定、易溶的试剂，可以与合适的助氧化剂以化学计量或催化形式使用。[1][2]

應用

过钌酸四丙基铵（TPAP）可以作为催化剂用于：     
  • 通过氧化反应将硫化物转化为砜。[2]       
  • 烯丙基醇的异构化，从而生成相应的饱和羰基衍生物。[3]      
  •  与N-甲基吗啉-N-氧化物（NMO）一起，用于将乙二醇裂解为羧酸。[4]

TPAP也可作为氧化剂用于：
  • 将苄醇氧化为苯甲醛，将甾醇氧化为相应的酮。[5][6]
  • 将N，N′-二羟基咪唑烷酮转换为硝酰基硝基氧自由基。[7]
  • 将羟基取代的三-N-三氟硼酸叔丁基铵氧化为醛和酮，且不伴有碳-硼键的断裂。[8][9]

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
STBJ9548
STBG1237V
STBD8558V
STBD8557V
STBD8559V

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Aldrichimica Acta, 23, 13-13 (1990)
Gary A Molander et al.
Journal of the American Chemical Society, 128(30), 9634-9635 (2006-07-27)
Potassium- and tetra-n-butylammonium organotrifluoroborates containing hydroxyl groups have been prepared and oxidized using several common oxidants. Aryl-, alkenyl-, and alkyltrifluoroborates containing both primary and secondary hydroxyl groups were oxidized in moderate to excellent yields with complete retention of the trifluoroborate
Tetrapropylammonium Perruthenate, Pr4N+RuO4 -, TPAP: A Catalytic Oxidant for Organic Synthesis
Steven V.L, et al.
Synthesis, 7, 639-666 (1994)
Ulyana Munoz Acuña et al.
Anticancer research, 37(4), 1617-1623 (2017-04-05)
The survival rate of women diagnosed with triple-negative breast-cancer (TNBC) remains low. Hence, this study aimed at the chemical and biological optimization of furanosteroid derivatives for the treatment of this type of malignancy using TNBC cells. Semi-synthetic analogs of wortmannolone
Brooks E Maki et al.
Organic letters, 11(7), 1651-1654 (2009-03-27)
Indoles and alcohols can be coupled in a dehydrogenative process catalyzed by tetrapropylammonium perruthenate. This efficient approach to indolylamides proceeds in a single flask under mild conditions. By employing substituted indoles and alkyl, branched, or benzylic alcohols, a variety of
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