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Merck

273031

Sigma-Aldrich

3-氯过氧苯甲酸

≤77%

别名:

氯过苯甲酸, 3-氯过氧苯甲酸, MCPBA

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About This Item

线性分子式:
ClC6H4CO3H
CAS号:
分子量:
172.57
Beilstein:
608317
MDL编号:
UNSPSC代码:
12352302
PubChem化学物质编号:
NACRES:
NA.22
价格与库存信息目前不能提供

方案

≤77%

表单

solid

反应适用性

reagent type: oxidant

mp

69-71 °C (lit.)

官能团

chloro
hydroperoxide

储存温度

2-8°C

SMILES字符串

OOC(=O)c1cccc(Cl)c1

InChI

1S/C7H5ClO3/c8-6-3-1-2-5(4-6)7(9)11-10/h1-4,10H

InChI key

NHQDETIJWKXCTC-UHFFFAOYSA-N

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一般描述

3-氯过苯甲酸是一种强氧化剂,主要用于烯烃的环氧化反应以及从酮到酯的Baeyer-Villiger氧化。[1][2]

应用

3-氯过苯甲酸已用于从N--甲苯基亚砜基-(E)-1-苯乙基亚胺至N--甲苯磺酰(E)-1-苯乙基亚胺的氧化,其中使用二氯甲烷作为溶剂。[3]它还用于制备单-和二-环氧-官能化的聚(3-羟基丁酸酯)基反应性聚合物。[4]MCPBA还是一种有效的氧化剂,用于将α-酰胺取代的聚酯转化为具有可调节热属性的相应聚砜。[5]
用于环氧化二-,三-和四-取代烯烃的有效氧化剂。

其他说明

残留物为 3-氯苯甲酸和水

警示用语:

Danger

危险分类

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Org. Perox. D - Skin Corr. 1C - Skin Sens. 1

储存分类代码

5.2 - Organic peroxides and self-reacting hazardous materials

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Lorenzo Gualandi et al.
Physical chemistry chemical physics : PCCP, 21(7), 3558-3563 (2018-09-20)
The synthesis of novel dibenzo-24-crown ether substituted nitroxides and their use as spin probes for the detection of cation guests by EPR are reported. Formation of a host-guest complex between the proposed spin probes and several cations, both organic and
Reactive mono-and di-epoxy-functionalized poly (3-hydroxybutyrate) s. Synthesis and characterization.
Michalak M
Polymer Degradation and Stability, 97(10), 1861-1870 (2012)
Rearrangements of organic peroxides and related processes.
Yaremenko I
Beilstein Journal of Organic Chemistry, 12, 1647-1647 (2016)
Shin Kamijo et al.
Organic letters, 12(18), 4195-4197 (2010-08-26)
The direct oxidation of ether sp(3) C-H bonds using the new reagent system mCPBA/CCl(3)CN/MeCN has been developed. CCl(3)CN in MeCN drastically alters the reactivity of m-chloroperbenzoic acid (mCPBA), and chemoselective transformation of methyl ethers to ketones was realized under mild
Marie Af Delgove et al.
Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986), 93(8), 2131-2140 (2018-08-03)
It is widely accepted that the poor thermostability of Baeyer-Villiger monooxygenases limits their use as biocatalysts for applied biocatalysis in industrial applications. The goal of this study was to investigate the biocatalytic oxidation of 3,3,5-trimethylcyclohexanone using a thermostable cyclohexanone monooxygenase

商品

The Baeyer-Villiger oxidation is the oxidative cleavage of a carbon-carbon bond adjacent to a carbonyl, which converts the ketones to esters and the cyclic ketones to lactones.

Baeyer-Villiger氧化是与羰基相邻的碳-碳键的氧化裂解,其可将酮转化为酯、环酮转化为内酯。

The Baeyer-Villiger oxidation is the oxidative cleavage of a carbon-carbon bond adjacent to a carbonyl, which converts the ketones to esters and the cyclic ketones to lactones.

The Baeyer-Villiger oxidation is the oxidative cleavage of a carbon-carbon bond adjacent to a carbonyl, which converts the ketones to esters and the cyclic ketones to lactones.

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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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