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Merck

289345

Sigma-Aldrich

氟化铯

99.9% trace metals basis

别名:

NSC 84270

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About This Item

经验公式(希尔记法):
CsF
CAS号:
分子量:
151.90
EC號碼:
MDL號碼:
分類程式碼代碼:
12352302
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

99.9% trace metals basis

mp

682 °C (lit.)

密度

4.115 g/mL at 25 °C (lit.)

SMILES 字串

[F-].[Cs+]

InChI

1S/Cs.FH/h;1H/q+1;/p-1

InChI 密鑰

XJHCXCQVJFPJIK-UHFFFAOYSA-M

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應用

可作为反应物用于:
  • 制备合成氟烯丙基化合物过程中的合成砌块
  • 在中性pH下和缓冲的有机-水混合溶液中,通过水解烷基甲硅烷基醚来合成醇
  • 炔基碘鎓盐的亲核氟化,以形成氟代乙烯基化合物
  • 亲核芳香取代(SNAr)反应
用于成功合成单晶Dion-Jacobson相CsLaTa2O7,其在光催化和超导性方面具有应用。
用作 Suzuki 交叉偶联反应合成邻取代联芳基化合物的碱。还用作质子介质(例如叔丁基和叔戊基醇)中主要卤化物和磺酸盐亲核氟化反应的试剂。

訊號詞

Danger

危險分類

Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Repr. 2 - STOT RE 2

標靶器官

Kidney,Adrenal gland

安全危害

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 2

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Journal of Organometallic Chemistry, 691, 5688-5688 (2006)
Dong Wook Kim et al.
Journal of the American Chemical Society, 128(50), 16394-16397 (2006-12-15)
Aprotic solvents are usually preferred for the SN2 reactions, because nucleophilicity and hence SN2 reactivity are severely retarded by the influence of the partial positive charge of protic solvents. In this work, we introduce a remarkable effect of using tertiary
L Bertollini et al.
Neuroreport, 5(5), 553-556 (1994-01-31)
The effect of intracellular fluoride ions on voltage-dependent calcium currents was tested during whole-cell voltage-clamp recordings in thalamic neurones acutely dissociated from young adult rats. It is demonstrated that 5-30 mM intracellular fluoride selectively and reversibly suppresses the high voltage-activated
J Kypr et al.
International journal of biological macromolecules, 13(1), 9-13 (1991-02-01)
Ten DNA fragments containing self-complementary alternating sequences of adenine and thymine differing in length and the starting nucleotide were studied by c.d. spectroscopy. It was found that d(TATATATA) but not d(ATATATAT), d(TATATA), d(CTATATAG) or (dT-dA)20 isomerized into the unusual X-DNA
S Nelson et al.
Science (New York, N.Y.), 265(5173), 774-777 (1994-08-05)
Neurons in the primary visual cortex of the cat are selectively activated by stimuli with particular orientations. This selectivity can be disrupted by the application of antagonists of the inhibitory neurotransmitter gamma-aminobutyric acid (GABA) to a local region of the

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