262056

二溴硼烷二甲基硫醚络合物 溶液

1.0 M in methylene chloride

• 别名: Dibromo(dimethyl sulfide)(hydro)boron solution, Dibromo(dimethyl sulfide)borane solution, Dibromoborane compound with dimethylsulfane solution, Dibromoborane dimethyl sulfide solution
• 线性分子式: (CH₃)₂S · BHBr₂
• CAS号: 55671-55-1
• 分子量: 233.76
• Beilstein: 4449985
• MDL號碼: MFCD00011601
• 分類程式碼代碼: 12352112
• PubChem物質ID: 24855855
• NACRES: NA.22

属性

• 形狀: liquid
• 反應適用性: reagent type: reductant
• 濃度: 1.0 M in methylene chloride
• 密度: 1.415 g/mL at 25 °C
• SMILES 字串: CSC.BrBBr
• InChI: 1S/C2H6S.BBr2H/c1-3-2;2-1-3/h1-2H3;1H
• InChI 密鑰: PGSRDLGPKTVELT-UHFFFAOYSA-N

说明

應用

Reactant for:

• Reductive elimination C-C bond forming reactions
• Lithiation-borylation reaction with Hoppe′s lithiated carbamates
• Preparation of boron analogues of uracil
• Boronation reactions for formation of cyclic boronium salts
• Hydroboration reactions
• Ring opening of terminal epoxides

安全信息

• 象形圖: GHS02,GHS08,GHS05,GHS07
• 訊號詞: Danger
• 危險聲明: H226,H261,H314,H336,H351
• 防範說明: P210 - P231 + P232 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• 危險分類: Carc. 2 - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - STOT SE 3 - Water-react 2
• 標靶器官: Central nervous system
• 安全危害: EUH014
• 儲存類別代碼: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: 80.6 °F - closed cup
• 閃點（°C）: 27 °C - closed cup
• 個人防護裝備: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter