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Merck

218790

Sigma-Aldrich

氯化四苯磷

98%

别名:

Chlorotetraphenylphosphorane

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About This Item

线性分子式:
(C6H5)4P(Cl)
CAS号:
分子量:
374.84
Beilstein:
3922393
EC 号:
MDL编号:
UNSPSC代码:
12352002
PubChem化学物质编号:
NACRES:
NA.22
价格与库存信息目前不能提供

方案

98%

表单

solid

mp

272-274 °C (lit.)

SMILES字符串

[Cl-].c1ccc(cc1)[P+](c2ccccc2)(c3ccccc3)c4ccccc4

InChI

1S/C24H20P.ClH/c1-5-13-21(14-6-1)25(22-15-7-2-8-16-22,23-17-9-3-10-18-23)24-19-11-4-12-20-24;/h1-20H;1H/q+1;/p-1

InChI key

WAGFXJQAIZNSEQ-UHFFFAOYSA-M

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应用

  • 四苯基氯化膦可用于调节 CH 3NH3PbI3 薄膜在沉积过程中的结晶度,以提高钙钛矿型太阳能电池 (PSCs) 器件的性能。[1]
  • 与有机金属阴离子络合物反应生成相应的盐。[2]
  • 在钯催化的 Heck 反应中也可作为芳基化试剂。[3]

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Oxoperoxo molybdenum (vi) and tungsten (vi) and oxodiperoxo molybdate (vi) and tungstate (vi) complexes with 8-quinolinol: synthesis, structure and catalytic activity.
Maiti S K, et al.
New. J. Chem., 29(4), 554-563 (2005)
Tetraarylphosphonium Halides as Arylating Reagents in Pd?Catalyzed Heck and Cross?Coupling Reactions.
Hwang L K, et al.
Angewandte Chemie (International Edition in English), 44(38), 6166-6169 (2005)
Efficient Perovskite Solar Cells with Reduced Photocurrent Hysteresis through Tuned Crystallinity of Hybrid Perovskite Thin Films.
Qi J, et al.
ACS Omega, 3(6), 7069-7076 (2018)
Do Kyun Kim et al.
Journal of microbiology and biotechnology, 23(3), 430-435 (2013-03-07)
Multidrug resistance, especially multidrug efflux mechanisms that extrude structurally unrelated cytotoxic compounds from the cell by multidrug transporters, is a serious problem and one of the main reasons for the failure of therapeutic treatment of infections by pathogenic microorganisms as
Yang Zhou et al.
Bioconjugate chemistry, 22(8), 1459-1472 (2011-06-24)
Alteration in mitochondrial transmembrane potential (ΔΨ(m)) is an important characteristic of cancer. The observation that the enhanced negative mitochondrial potential is prevalent in tumor cell phenotype provides a conceptual basis for development of mitochondrion-targeting therapeutic drugs and molecular imaging probes.

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