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Merck

167525

Sigma-Aldrich

氯甲酸苯酯

99%

别名:

苯基氯甲酸酯

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About This Item

线性分子式:
ClCOOC6H5
CAS号:
分子量:
156.57
Beilstein:
606778
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

蒸汽密度

1 (vs air)

品質等級

蒸汽壓力

1.22 psi ( 20 °C)
1.67 psi ( 55 °C)

化驗

99%

形狀

liquid

折射率

n20/D 1.511 (lit.)

bp

74-75 °C/13 mmHg (lit.)

密度

1.248 g/mL at 25 °C (lit.)

官能基

chloro
phenoxy

儲存溫度

2-8°C

SMILES 字串

ClC(=O)Oc1ccccc1

InChI

1S/C7H5ClO2/c8-7(9)10-6-4-2-1-3-5-6/h1-5H

InChI 密鑰

AHWALFGBDFAJAI-UHFFFAOYSA-N

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一般說明

研究了氯甲酸苯酯在水-乙二醇、阳离子、两性离子、非离子和阴离子胶束溶液中的自发水解动力学,

應用

氯甲酸苯酯已被用于聚(2-(苯氧基羰氧基)甲基丙烯酸乙酯)和苯基-(4-乙烯基苯基)碳酸的合成。

象形圖

Skull and crossbonesCorrosion

訊號詞

Danger

危險分類

Acute Tox. 1 Inhalation - Acute Tox. 4 Oral - Met. Corr. 1 - Skin Corr. 1B - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

156.2 °F - closed cup

閃點(°C)

69 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Amalia Rodríguez et al.
Langmuir : the ACS journal of surfaces and colloids, 20(23), 9945-9952 (2004-11-03)
The spontaneous hydrolysis of phenyl chloroformate was studied in water-ethylene glycol, EG, cationic, zwitterionic, nonionic, and anionic micellar solutions, the surfactants being tetradecyltrimethylammonium bromide, tetradecyl-N,N-dimethyl-3-ammonio-1-propanesulfonate, tricosaoxyethylene glycol ether, and sodium dodecyl sulfate. The dependence of the observed rate constant on
Synthesis and ligand recognition of paracetamol selective polymers: semi-covalent versus non-covalent molecular imprinting.
Rosengren-Holmberg JP, et al.
Organic & Biomolecular Chemistry, 7(15), 3148-3155 (2009)
R K Keller et al.
Biochemistry, 20(20), 5831-5836 (1981-09-29)
A sensitive assay is described for quantitating dolichyl phosphate (Dol-P), the polyprenyl phospholipid which participates in N-linked glycosylation. The assay is based on a novel reaction of alkyl phosphates with phenyl chloroformate in which a monosubstituted mixed anhydride of phosphoric
Luis García-Río et al.
Langmuir : the ACS journal of surfaces and colloids, 21(17), 7672-7679 (2005-08-11)
A study was carried out on the solvolysis of substituted phenyl chloroformates in AOT/isooctane/water microemulsions. (AOT is the sodium salt of bis(2-ethyhexyl)sulfosuccinate.) The results obtained have been interpreted by taking into account the distribution of the chloroformates between the continuous
K Anzai et al.
Nucleic acids symposium series, (15)(15), 49-52 (1984-01-01)
Reaction of 2',3'-O-isopropylideneadenosine with p-toluyl chloride in a mixture of methylene chloride and triethylamine afforded 2',3'-O-isopropylidene-N,N,5'-O-tri-p-toluyladenosine (8)(30%), 8,5'-O-cycloadenosine derivatives 9 (34%) and 10 (11%), and a cyanoimidazole nucleoside 11 (12%).

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