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16490

Sigma-Aldrich

溴丙酮酸

≥98.0%

别名:

3-溴-2-氧代丙酸

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About This Item

线性分子式:
BrCH2COCOOH
CAS号:
1113-59-3
分子量:
166.96
Beilstein:
1746786
EC 号:
214-206-5
MDL编号:
MFCD00002587
UNSPSC代码:
12352100
PubChem化学物质编号:
57647568
NACRES:
NA.22

质量水平

200

方案

≥98.0%

表单

(Powder or Crystals or Flakes)

mp

77-82 °C

溶解性

water: soluble 1 g/10 mL, clear to very slightly hazy, colorless

官能团

bromo
carboxylic acid
ketone

储存温度

2-8°C

SMILES字符串

OC(=O)C(=O)CBr

InChI

1S/C3H3BrO3/c4-1-2(5)3(6)7/h1H2,(H,6,7)

InChI key

PRRZDZJYSJLDBS-UHFFFAOYSA-N

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相关类别

一般描述

可能含有痕量的二溴丙酮酸
溴丙酮酸是半胱氨酸残基的亲和标记物 †。作为核酸和蛋白质之间的交联剂 。已经研究了溴丙酮酸灭活胰腺核糖核酸酶 A 的动力学 。

应用

将溴丙酮酸用于咪唑并 [1,2- a ] 吡啶-2-羧酸的合成 。

其他说明

半胱氨酸残基的亲和标记；核酸与蛋白质的交联剂

象形图

Corrosion
GHS05

警示用语：

Danger

危险声明

H314

危险分类

Eye Dam. 1 - Skin Corr. 1B

储存分类代码

8A - Combustible corrosive hazardous materials

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
BCCK1798
BCCK1409
BCCJ9220
0000210609
0000210608

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I Kameshita et al.
Journal of biochemistry, 86(5), 1251-1257 (1979-11-01)
Phosphoenolpyruvate carboxylase [EC 4.1.1.31] from Escherichia coli W was alkylated by incubation with bromopyruvate, substrate analog, leading to irreversible inactivation. The reaction followed pseudo-first-order kinetics. Mg2+, an essential cofactor for catalysis, enhanced the inactivation, and the enhancing effect increased as
Ananda Herath et al.
Organic letters, 12(3), 412-415 (2009-12-30)
The first continuous flow synthesis of imidazo[1,2-a]pyridine-2-carboxylic acids directly from 2-aminopyridines and bromopyruvic acid has been developed, representing a significant advance over the corresponding in-flask method. The process was applied to the multistep synthesis of imidazo[1,2-a]pyridine-2-carboxamides, including a Mur ligase
M H Wang et al.
The Biochemical journal, 320 ( Pt 1), 187-192 (1996-11-15)
The kinetic theory of substrate reaction during the modification of enzyme activity [Duggleby (1986) J. Theor. Biol. 123, 67-80; Wang and Tsou (1990) J. Theor. Biol. 142, 531-549] has been applied to a study of the inactivation kinetics of ribonuclease
N Nitta et al.
FEBS letters, 166(1), 194-198 (1984-01-23)
Cytosine in nucleic acids can be converted into N4-aminocytosine by treatment with a mixture of hydrazine and bisulfite. The hydrazino group thus formed at position 4 of the pyrimidine ring can be linked to a sulhydryl group in proteins by
P M Alliel et al.
European journal of biochemistry, 105(2), 343-351 (1980-04-01)
We have reported in a previous communication a kinetic study showing bromopyruvate to behave as an active-site-directed reagent for flavocytochrome b2. It is shown here that inactivation is accompanied by incorporation of 3 mol reagent/subunit of oxidized intact enzyme and
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