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Merck

156876

Sigma-Aldrich

N-羟乙基苯胺

98%

别名:

2-苯氨基乙醇, 2-苯胺乙醇, N-苯基乙醇胺

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About This Item

线性分子式:
C6H5NHCH2CH2OH
CAS号:
分子量:
137.18
Beilstein:
774672
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

蒸汽密度

>1 (vs air)

品質等級

蒸汽壓力

<0.01 mmHg ( 20 °C)

化驗

98%

形狀

liquid

折射率

n20/D 1.578 (lit.)

bp

278-282 °C/760 mmHg (lit.)

密度

1.094 g/mL at 25 °C (lit.)

SMILES 字串

OCCNc1ccccc1

InChI

1S/C8H11NO/c10-7-6-9-8-4-2-1-3-5-8/h1-5,9-10H,6-7H2

InChI 密鑰

MWGATWIBSKHFMR-UHFFFAOYSA-N

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應用

N-(2-羟乙基)苯胺被用作人嗅觉UDP-葡糖醛酸糖基转移酶的底物。

訊號詞

Danger

危險分類

Acute Tox. 2 Dermal - Acute Tox. 3 Oral - Aquatic Chronic 2 - Eye Dam. 1 - STOT RE 2 - STOT SE 1

標靶器官

Blood, Blood,hematopoietic system

儲存類別代碼

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

235.4 °F - closed cup

閃點(°C)

113 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Santos Fustero et al.
The Journal of organic chemistry, 74(11), 4429-4432 (2009-05-15)
The preparation of cyclic dipeptide mimetics from chiral imino lactones derived from (R)-phenylglycinol is described. Key steps of the synthetic route included the fully stereoselective construction of a quaternary center, the formation of six-, seven-, or eight-membered lactams by means
Mercedes Amat et al.
The Journal of organic chemistry, 71(10), 3804-3815 (2006-05-06)
The stereochemical outcome of the alkylation of a variety of phenylglycinol-derived oxazolopiperidone lactams is studied. The influence of the configuration of the C-8a stereocenter and the effect of the substituents at the C-8 and C-8a positions on the stereoselectivity of
Mercedes Amat et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 12(30), 7872-7881 (2006-07-20)
A straightforward procedure for the synthesis of enantiopure polysubstituted piperidines is reported. It involves the direct generation of chiral non-racemic oxazolo[3,2-a]piperidone lactams that already incorporate carbon substituents on the heterocyclic ring and the subsequent removal of the chiral auxiliary. The
N Philippe et al.
Organic letters, 2(15), 2185-2187 (2000-08-10)
Highly diastereoselective protonation of chiral lactam enolates of 4-substituted-1,4-dihydroisoquinolin-3-ones is reported. Protonation and alkylation processes of these lactam enolates derived from phenylglycinol occur with opposite diastereofacial selectivity. This diastereoselective protonation has been applied to the asymmetric synthesis of (4S)-N-methyl-4-phenyl-1,2,3,4-tetrahydroisoquinoline 9
Mercedes Amat et al.
The Journal of organic chemistry, 69(25), 8681-8693 (2004-12-04)
The stereochemical outcome of the conjugate addition of a variety of stabilized nucleophiles (2-indoleacetic enolates and sulfur-stabilized anions) to the phenylglycinol-derived unsaturated lactams trans-2, cis-2, and its 8-ethyl-substituted analogue 10 is studied. The factors governing the exo or endo facial

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