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Merck

143995

Sigma-Aldrich

炔丙氯

98%

别名:

3-氯丙炔

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About This Item

线性分子式:
HC≡CCH2Cl
CAS号:
分子量:
74.51
Beilstein:
506005
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

化驗

98%

形狀

liquid

折射率

n20/D 1.435 (lit.)

bp

58 °C (lit.)

溶解度

benzene: miscible
chloroform: miscible
diethyl ether: miscible
ethanol: miscible
ethyl acetate: miscible
ethylene glycol: miscible
water: insoluble

密度

1.03 g/mL at 25 °C (lit.)

儲存溫度

2-8°C

SMILES 字串

ClCC#C

InChI

1S/C3H3Cl/c1-2-3-4/h1H,3H2

InChI 密鑰

LJZPPWWHKPGCHS-UHFFFAOYSA-N

一般說明

炔丙氯是一种有效的炔丙基化剂。它可通过脉冲激光光解生成炔丙基

應用

炔丙氯已用于在199 nm下研究光激发时解离的炔丙氯的发射光谱。它已用于合成双酚A的新型四芳基类似物和双酚A炔丙基树脂的三芳基类似物

訊號詞

Danger

危險分類

Acute Tox. 3 Oral - Flam. Liq. 2 - Skin Corr. 1B

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 2

閃點(°F)

66.2 °F - closed cup

閃點(°C)

19 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles


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Investigating the C-Cl Antibonding Character in the pp* Excited State of Vinyl, Allyl, and Propargyl Chloride: Emission Spectra and ab Initio Calculations.
Browning PW, et al.
The Journal of Physical Chemistry, 100(19), 7765-7771 (1996)
Akira Matsugi et al.
The journal of physical chemistry. A, 115(26), 7610-7624 (2011-05-24)
The kinetics and mechanisms of the self-reaction of allyl radicals and the cross-reaction between allyl and propargyl radicals were studied both experimentally and theoretically. The experiments were carried out over the temperature range 295-800 K and the pressure range 20-200
DIPROPARGYL ETHERS OF HIGH ASPECT RATIO BISPHENOLS.
Filipova TS, et al.
Polymer Preprints (American Chemical Society, Division of Polymer Chemistry), 48(1), 388-388 (2007)
Lyudmila A Grischenko et al.
Carbohydrate research, 376, 7-14 (2013-06-04)
New arabinogalactan propargyl ethers with degree of substitution (DS) up to 2.8 have been obtained by propargylation of arabino-3,6-galactan (AG) with propargyl bromide (PB) in the two-phase system 30-60% КОН aqueous solution/toluene in the presence of triethylbenzylammonium chloride (TEBAС) or

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