249866

Titan(IV)-chlorid -Lösung

1.0 M in methylene chloride

• Synonym(e): Titantetrachlorid -Lösung
• Lineare Formel: TiCl₄
• CAS-Nummer: 7550-45-0
• Molekulargewicht: 189.68
• MDL-Nummer: MFCD00011267
• UNSPSC-Code: 12352300
• PubChem Substanz-ID: 329752763
• NACRES: NA.55
• Form: liquid

Eigenschaften

• Dampfdruck: 24.09 psi ( 55 °C); 6.93 psi ( 20 °C)
• Qualitätsniveau: 100
• Form: liquid
• Eignung der Reaktion: reagent type: catalyst; core: titanium
• Konzentration: 0.95-1.10 M NaOH (titration); 1.0 M in methylene chloride
• Dichte: 1.365 g/mL at 25 °C
• SMILES String: Cl[Ti](Cl)(Cl)Cl
• InChI: 1S/4ClH.Ti/h4*1H;/q;;;;+4/p-4
• InChIKey: XJDNKRIXUMDJCW-UHFFFAOYSA-J

Beschreibung

Allgemeine Beschreibung

Titanium(IV) chloride participates in the Baylis-Hillman reaction of arylaldehydes with methyl vinyl ketone. Neutral solutions of TiCl₄ having a pH in the range of 2.5 to 6.0 (prepared by the addition of magnesium oxide as a base) are used to synthesize nanosized titanium dioxide.

Anwendung

Activates pyrrolidines for improved conversion, via a modified Bouveault reaction, to the corresponding α,α-dimethylamines.

Sicherheitshinweise

• Piktogramme: GHS06,GHS08,GHS05
• Signalwort: Danger
• H-Sätze: H314,H331,H336,H351
• P-Sätze: P202 - P261 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Gefahreneinstufungen: Acute Tox. 3 Inhalation - Carc. 2 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
• Zielorgane: Central nervous system
• Zusätzliche Gefahrenhinweise: EUH014
• Lagerklassenschlüssel: 6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
• WGK: WGK 2
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable